Quantitative Voltammetry in Weakly Supported Media. Two Electron Transfer, Chronoamperometry of Electrodeposition and Stripping for Cadmium at Microhemispherical Mercury Electrodes
Double potential step chronoamperometry for the two-electron transfer amalgam-forming deposition and stripping of cadmium at a hemispherical mercury electrode in aqueous solution containing different concentrations of supporting electrolyte is compared with simulated results using the Nernst-Planck-...
| Hlavní autoři: | , , , |
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| Médium: | Journal article |
| Jazyk: | English |
| Vydáno: |
2009
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| _version_ | 1826273116533293056 |
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| author | Limon-Petersen, J Dickinson, E Rees, N Compton, R |
| author_facet | Limon-Petersen, J Dickinson, E Rees, N Compton, R |
| author_sort | Limon-Petersen, J |
| collection | OXFORD |
| description | Double potential step chronoamperometry for the two-electron transfer amalgam-forming deposition and stripping of cadmium at a hemispherical mercury electrode in aqueous solution containing different concentrations of supporting electrolyte is compared with simulated results using the Nernst-Planck-Poisson system of equations. The latter were generated using an approximation of zero electric field at the interface [J. Phys. Chem. C 2008, 112, 13716-13728]; the approximation gives a good agreement between theory and experiment, so validating its use for the description of macroelectrode and microelectrode (but not nanoelectrode) problems involving low or negligible levels of supporting electrolyte. © 2009 American Chemical Society. |
| first_indexed | 2024-03-06T22:23:17Z |
| format | Journal article |
| id | oxford-uuid:55ca835b-80d8-4c64-8fe0-19e93cadf9b6 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T22:23:17Z |
| publishDate | 2009 |
| record_format | dspace |
| spelling | oxford-uuid:55ca835b-80d8-4c64-8fe0-19e93cadf9b62022-03-26T16:46:23ZQuantitative Voltammetry in Weakly Supported Media. Two Electron Transfer, Chronoamperometry of Electrodeposition and Stripping for Cadmium at Microhemispherical Mercury ElectrodesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:55ca835b-80d8-4c64-8fe0-19e93cadf9b6EnglishSymplectic Elements at Oxford2009Limon-Petersen, JDickinson, ERees, NCompton, RDouble potential step chronoamperometry for the two-electron transfer amalgam-forming deposition and stripping of cadmium at a hemispherical mercury electrode in aqueous solution containing different concentrations of supporting electrolyte is compared with simulated results using the Nernst-Planck-Poisson system of equations. The latter were generated using an approximation of zero electric field at the interface [J. Phys. Chem. C 2008, 112, 13716-13728]; the approximation gives a good agreement between theory and experiment, so validating its use for the description of macroelectrode and microelectrode (but not nanoelectrode) problems involving low or negligible levels of supporting electrolyte. © 2009 American Chemical Society. |
| spellingShingle | Limon-Petersen, J Dickinson, E Rees, N Compton, R Quantitative Voltammetry in Weakly Supported Media. Two Electron Transfer, Chronoamperometry of Electrodeposition and Stripping for Cadmium at Microhemispherical Mercury Electrodes |
| title | Quantitative Voltammetry in Weakly Supported Media. Two Electron Transfer, Chronoamperometry of Electrodeposition and Stripping for Cadmium at Microhemispherical Mercury Electrodes |
| title_full | Quantitative Voltammetry in Weakly Supported Media. Two Electron Transfer, Chronoamperometry of Electrodeposition and Stripping for Cadmium at Microhemispherical Mercury Electrodes |
| title_fullStr | Quantitative Voltammetry in Weakly Supported Media. Two Electron Transfer, Chronoamperometry of Electrodeposition and Stripping for Cadmium at Microhemispherical Mercury Electrodes |
| title_full_unstemmed | Quantitative Voltammetry in Weakly Supported Media. Two Electron Transfer, Chronoamperometry of Electrodeposition and Stripping for Cadmium at Microhemispherical Mercury Electrodes |
| title_short | Quantitative Voltammetry in Weakly Supported Media. Two Electron Transfer, Chronoamperometry of Electrodeposition and Stripping for Cadmium at Microhemispherical Mercury Electrodes |
| title_sort | quantitative voltammetry in weakly supported media two electron transfer chronoamperometry of electrodeposition and stripping for cadmium at microhemispherical mercury electrodes |
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