On the adiabaticity of electrode processes: Effect of the supporting electrolyte cation on the kinetics of electroreduction of 3-nitrophenolate

On the adiabaticity of electrode processes: Effect of the supporting electrolyte cation on the kinetics of electroreduction of 3-nitrophenolate

The comparative analysis of voltammetric responses at different temperatures through the asymmetric Marcus-Hush theory provides physical insight into the changes upon the electron transfer mechanism and the electronic interaction between the electrode and the electroactive species. Herein this appro...

Volledige beschrijving

Bibliografische gegevens
Hoofdauteurs:	Laborda, E, Batchelor-McAuley, C, Suwatchara, D, Henstridge, M, Compton, R
Formaat:	Journal article
Taal:	English
Gepubliceerd in:	2013

Gelijkaardige items

A theoretical and experimental approach to the adiabaticity of diffusional electron transfer processes. Electroreduction of 2-nitropropane on mercury microelectroelectrodes
door: Laborda, E, et al.
Gepubliceerd in: (2013)

Electrode kinetics at carbon electrodes and the density of electronic states.
door: Nissim, R, et al.
Gepubliceerd in: (2012)

Reply to comments contained in "Are the reactions of quinones on graphite adiabatic?", by N.B. Luque, W. Schmickler [Electrochim. Acta xx (2012) yyy]
door: Batchelor-McAuley, C, et al.
Gepubliceerd in: (2013)

Tafel-Volmer electrode reactions: The influence of electron-transfer kinetics
door: Lin, C, et al.
Gepubliceerd in: (2015)

Comparative evaluation of the symmetric and asymmetric Marcus-Hush formalisms of electrode kinetics - The one-electron oxidation of tetraphenylethylene in dichloromethane on platinum microdisk electrodes
door: Suwatchara, D, et al.
Gepubliceerd in: (2012)

Giving physical insight into the Butler-Volmer model of electrode kinetics: Application of asymmetric Marcus-Hush theory to the study of the electroreductions of 2-methyl-2-nitropropane, cyclooctatetraene and europium(III) on mercury microelectrodes
door: Henstridge, M, et al.
Gepubliceerd in: (2012)

Experimental comparison of the Butler-Volmer and Marcus-Hush-Chidsey formalisms of electrode kinetics: The reduction of cyclooctatetraene at mercury hemispherical electrodes via cyclic and square wave voltammetries
door: Suwatchara, D, et al.
Gepubliceerd in: (2011)

Experimental comparison of the Butler-Volmer and Marcus-Hush-Chidsey formalisms of electrode kinetics: The reduction of cyclooctatetraene at mercury hemispherical electrodes via cyclic and square wave voltammetries
door: Suwatchara, D, et al.
Gepubliceerd in: (2012)

Application of Marcus-Hush-Chidsey Theory to Two Electron Systems. The Influence of Electrode Material on the Electro-Reduction Kinetics of Covalently Attached 2-Anthraquinonyl Groups: Gold Vs. Carbon
door: Kozub, B, et al.
Gepubliceerd in: (2011)

Reply to comments contained in "are the reactions of quinones on graphite adiabatic?", by N.B. Luque, W. Schmickler [Electrochim. Acta xx (2012) yyy]
door: Batchelor-Mcauley, C, et al.
Gepubliceerd in: (2013)

Thin-Film Modified Rotating Disk Electrodes: Models of Electron-Transfer Kinetics for Passive and Electroactive Films
door: Batchelor-McAuley, C, et al.
Gepubliceerd in: (2014)

Carbon dioxide reduction in room temperature ionic liquids: the effect of the choice of electrode material, cation, and anion
door: Tanner, E, et al.
Gepubliceerd in: (2016)

Variable temperature study of electro-reduction of 3-nitrophenolate via cyclic and square wave voltammetry: Molecular insights into electron transfer processes based on the asymmetric Marcus-Hush model
door: Laborda, E, et al.
Gepubliceerd in: (2013)

Variable temperature study of electro-reduction of 3-nitrophenolate via cyclic and square wave voltammetry: Molecular insights Into electron transfer processes based on the asymmetric Marcus-Hush model
door: Laborda, E, et al.
Gepubliceerd in: (2013)

Asymmetric Marcus theory: Application to electrode kinetics
door: Laborda, E, et al.
Gepubliceerd in: (2012)

Asymmetric Marcus-Hush theory for voltammetry.
door: Laborda, E, et al.
Gepubliceerd in: (2013)

Edge plane pyrolytic graphite electrode covalently modified with 2-anthraquinonyl groups: theory and experiment.
door: Kozub, B, et al.
Gepubliceerd in: (2011)

Marcus-Hush-Chidsey theory of electron transfer to and from species bound at a non-uniform electrode surface: Theory and experiment
door: Henstridge, M, et al.
Gepubliceerd in: (2011)

Voltammetric selectivity conferred by the modification of electrodes using conductive porous layers or films: The oxidation of dopamine on glassy carbon electrodes modified with multiwalled carbon nanotubes
door: Henstridge, M, et al.
Gepubliceerd in: (2010)

Experimental Comparison of the Marcus-Hush and Butler-Volmer Descriptions of Electrode Kinetics. The One-Electron Oxidation of 9,10-Diphenylanthracene and One-Electron Reduction of 2-Nitropropane Studied at High-Speed Channel Microband Electrodes
door: Suwatchara, D, et al.
Gepubliceerd in: (2011)

Steady-state voltammetry at a microdisc electrode in the absence of excess supporting electrolyte for reversible, quasi-reversible and irreversible electrode kinetics.
door: Belding, SR, et al.
Gepubliceerd in: (2012)

Electrochemical measurement of the dissolved oxygen concentration in water in the absence of deliberately added supporting electrolyte
door: Clark, R, et al.
Gepubliceerd in: (2017)

Voltammetry of multi-electron electrode processes of organic species
door: Batchelor-McAuley, C, et al.
Gepubliceerd in: (2012)

Glassy carbon tubular electrodes for the reduction of oxygen to hydrogen peroxide.
door: Li, Q, et al.
Gepubliceerd in: (2013)

A flow system for hydrogen peroxide production at reticulated vitreous carbon via electroreduction of oxygen
door: Li, Q, et al.
Gepubliceerd in: (2014)

Electrolyte tuning of electrode potentials: the one electron vs. two electron reduction of anthraquinone-2-sulfonate in aqueous media.
door: Li, Q, et al.
Gepubliceerd in: (2011)

Use of 'split waves' for the measurement of electrocatalytic kinetics: methyl viologen mediated oxygen reduction on a boron-doped diamond electrode.
door: Lin, Q, et al.
Gepubliceerd in: (2013)

Oxygen Electroreduction at High-Index Pt Electrodes in Alkaline Electrolytes: A Decisive Role of the Alkali Metal Cations
door: Batyr Garlyyev, et al.
Gepubliceerd in: (2018-11-01)

Aqueous voltammetry in the near absence of electrolyte
door: Li, X, et al.
Gepubliceerd in: (2017)

Electrochemical oxidation of guanine: electrode reaction mechanism and tailoring carbon electrode surfaces to switch between adsorptive and diffusional responses.
door: Li, Q, et al.
Gepubliceerd in: (2010)

Differential pulse techniques in weakly supported media: Changes in the kinetics and thermodynamics of electrode processes resulting from the supporting electrolyte concentration
door: Wang, Y, et al.
Gepubliceerd in: (2012)

Experimental advances in electrode kinetics
door: Suwatchara, D
Gepubliceerd in: (2013)

Giving physical insight into the Butler-Volmer model of electrode kinetics: Part 2-Nonlinear solvation effects on the voltammetry of heterogeneous electron transfer processes
door: Laborda, E, et al.
Gepubliceerd in: (2012)

Thin film-modified electrodes: a model for the charge transfer resistance in electrochemical impedance spectroscopy
door: Eloul, S, et al.
Gepubliceerd in: (2014)

'Sticky electrodes' for the detection of silver nanoparticles.
door: Tschulik, K, et al.
Gepubliceerd in: (2013)

Studies in electrode kinetics
door: Henstridge, MC
Gepubliceerd in: (2013)

Methyl viologen mediated oxygen reduction in ethanol solvent: the electrocatalytic reactivity of the radical cation
door: Lin, Q, et al.
Gepubliceerd in: (2013)

Redox systems obeying Marcus-Hush-Chidsey electrode kinetics do not obey the Randles-Sevcik equation for linear sweep voltammetry
door: Henstridge, M, et al.
Gepubliceerd in: (2012)

Electrode-particle impacts: a users guide
door: Sokolov, S, et al.
Gepubliceerd in: (2016)

The contrasting behaviour of polycrystalline bulk gold and gold nanoparticle modified electrodes towards the underpotential deposition of thallium
door: Batchelor-McAuley, C, et al.
Gepubliceerd in: (2008)