Straightforward synthesis of alpha,beta-epoxysilanes from terminal epoxides by lithium 2,2,6,6-tetramethylpiperidide-mediated deprotonation-in situ silylation
Lithiation-in situ silylation of simple terminal epoxides using lithium 2,2,6,6-tetramethylpiperidide in combination with trimethylsilyl chloride provides a direct and experimentally convenient process for the synthesis of trans-α,β-epoxysilanes. © 2002 Elsevier Science Ltd. All rights reserved.
Үндсэн зохиолчид: | Hodgson, D, Reynolds, N, Coote, S |
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Формат: | Journal article |
Хэл сонгох: | English |
Хэвлэсэн: |
2002
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Ижил төстэй зүйлс
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The reactivity of epoxides with lithium 2,2,6,6-tetramethylpiperidide in combination with organolithiums or grignard reagents.
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First direct deprotonation-electrophile trapping of simple epoxides: synthesis of alpha,beta-epoxysilanes from terminal epoxides.
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Organolithiums and lithium 2,2,6,6-tetramethylpiperidide in reductive alkylation of epoxides: Synthesis of (E)-alkenes [(E)-2-methyltetradeca-1,3- diene]
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Deprotonation-electrophile trapping of terminal epoxides.
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