Concise syntheses of the natural products (+)-sylvaticin and (+)-cis-sylvaticin.

Two concise syntheses of the natural products cis-sylvaticin and sylvaticin are reported, using oxidative cyclization methodology as the key step. A sequential solvolysis/hydride shift/intramolecular reduction cascade was used to establish the trans stereochemistry of one of the THF rings of sylvati...

תיאור מלא

מידע ביבליוגרפי
Main Authors: Donohoe, T, Harris, R, Williams, O, Hargaden, G, Burrows, J, Parker, J
פורמט: Journal article
שפה:English
יצא לאור: 2009
תיאור
סיכום:Two concise syntheses of the natural products cis-sylvaticin and sylvaticin are reported, using oxidative cyclization methodology as the key step. A sequential solvolysis/hydride shift/intramolecular reduction cascade was used to establish the trans stereochemistry of one of the THF rings of sylvaticin.