Concise syntheses of the natural products (+)-sylvaticin and (+)-cis-sylvaticin.
Two concise syntheses of the natural products cis-sylvaticin and sylvaticin are reported, using oxidative cyclization methodology as the key step. A sequential solvolysis/hydride shift/intramolecular reduction cascade was used to establish the trans stereochemistry of one of the THF rings of sylvati...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Jezik: | English |
| Izdano: |
2009
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| _version_ | 1826273321842376704 |
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| author | Donohoe, T Harris, R Williams, O Hargaden, G Burrows, J Parker, J |
| author_facet | Donohoe, T Harris, R Williams, O Hargaden, G Burrows, J Parker, J |
| author_sort | Donohoe, T |
| collection | OXFORD |
| description | Two concise syntheses of the natural products cis-sylvaticin and sylvaticin are reported, using oxidative cyclization methodology as the key step. A sequential solvolysis/hydride shift/intramolecular reduction cascade was used to establish the trans stereochemistry of one of the THF rings of sylvaticin. |
| first_indexed | 2024-03-06T22:26:25Z |
| format | Journal article |
| id | oxford-uuid:56ced301-a64d-40a3-a3b7-7856855b69a4 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T22:26:25Z |
| publishDate | 2009 |
| record_format | dspace |
| spelling | oxford-uuid:56ced301-a64d-40a3-a3b7-7856855b69a42022-03-26T16:52:44ZConcise syntheses of the natural products (+)-sylvaticin and (+)-cis-sylvaticin.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:56ced301-a64d-40a3-a3b7-7856855b69a4EnglishSymplectic Elements at Oxford2009Donohoe, THarris, RWilliams, OHargaden, GBurrows, JParker, JTwo concise syntheses of the natural products cis-sylvaticin and sylvaticin are reported, using oxidative cyclization methodology as the key step. A sequential solvolysis/hydride shift/intramolecular reduction cascade was used to establish the trans stereochemistry of one of the THF rings of sylvaticin. |
| spellingShingle | Donohoe, T Harris, R Williams, O Hargaden, G Burrows, J Parker, J Concise syntheses of the natural products (+)-sylvaticin and (+)-cis-sylvaticin. |
| title | Concise syntheses of the natural products (+)-sylvaticin and (+)-cis-sylvaticin. |
| title_full | Concise syntheses of the natural products (+)-sylvaticin and (+)-cis-sylvaticin. |
| title_fullStr | Concise syntheses of the natural products (+)-sylvaticin and (+)-cis-sylvaticin. |
| title_full_unstemmed | Concise syntheses of the natural products (+)-sylvaticin and (+)-cis-sylvaticin. |
| title_short | Concise syntheses of the natural products (+)-sylvaticin and (+)-cis-sylvaticin. |
| title_sort | concise syntheses of the natural products sylvaticin and cis sylvaticin |
| work_keys_str_mv | AT donohoet concisesynthesesofthenaturalproductssylvaticinandcissylvaticin AT harrisr concisesynthesesofthenaturalproductssylvaticinandcissylvaticin AT williamso concisesynthesesofthenaturalproductssylvaticinandcissylvaticin AT hargadeng concisesynthesesofthenaturalproductssylvaticinandcissylvaticin AT burrowsj concisesynthesesofthenaturalproductssylvaticinandcissylvaticin AT parkerj concisesynthesesofthenaturalproductssylvaticinandcissylvaticin |