Exploration of composition space in templated uranium sulfates.
The phase stability of organically templated uranium sulfates in the [UO(2)(CH(3)CO(2))(2).2H(2)O/homopiperazine/H(2)SO(4)] and [UO(2)(CH(3)CO(2))(2).2H(2)O/N,N-dimethylethylenediamine/H(2)SO(4)] systems has been studied using composition space. Two new compounds were formed in each system; [N(2)C(5...
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| Format: | Journal article |
| Language: | English |
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2003
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| _version_ | 1797069634466217984 |
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| author | Doran, M Norquist, A O'Hare, D |
| author_facet | Doran, M Norquist, A O'Hare, D |
| author_sort | Doran, M |
| collection | OXFORD |
| description | The phase stability of organically templated uranium sulfates in the [UO(2)(CH(3)CO(2))(2).2H(2)O/homopiperazine/H(2)SO(4)] and [UO(2)(CH(3)CO(2))(2).2H(2)O/N,N-dimethylethylenediamine/H(2)SO(4)] systems has been studied using composition space. Two new compounds were formed in each system; [N(2)C(5)H(14)](2)[UO(2)(SO(4))(3)] (USO-17) and [N(2)C(5)H(14)][UO(2)(H(2)O)(SO(4))(2)] (USO-18) contain homopiperazine, and [N(2)C(4)H(14)][UO(2)(SO(4))(2)] (USO-19) and [N(2)C(4)H(14)][(UO(2))(2)(H(2)O)(SO(4))(3)].H(2)O (USO-20) contain N,N-dimethylethylenediamine. The relative stability of the products from each system is dependent upon the reactant mole fractions in the initial reaction gel. Crystal data: USO-17, a = 14.4975(3) A, b = 11.9109(3) A, c = 13.0157(3) A, beta = 110.475(1) degrees, monoclinic, C2/c (No. 15), Z = 4; for USO-18, a = 7.6955(2) A, b = 11.7717(3) A, c = 14.7038(4) A, orthorhombic, P22(1)2(1) (No. 18), Z = 4; for USO-19, a = 9.3322(1) A, b = 9.7743(2) A, c = 13.8897(3) A, orthorhombic, P2(1)2(1)2(1) (No. 19), Z = 4; and for USO-20, a = 11.2460(2) A, b = 10.5387(2) A, c = 17.0432(3) A, beta = 92.9884(6) degrees, monoclinic, P2(1)/c (No. 14), Z = 4. |
| first_indexed | 2024-03-06T22:27:22Z |
| format | Journal article |
| id | oxford-uuid:571adafc-b133-4b01-8a52-a4174e909247 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T22:27:22Z |
| publishDate | 2003 |
| record_format | dspace |
| spelling | oxford-uuid:571adafc-b133-4b01-8a52-a4174e9092472022-03-26T16:54:36ZExploration of composition space in templated uranium sulfates.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:571adafc-b133-4b01-8a52-a4174e909247EnglishSymplectic Elements at Oxford2003Doran, MNorquist, AO'Hare, DThe phase stability of organically templated uranium sulfates in the [UO(2)(CH(3)CO(2))(2).2H(2)O/homopiperazine/H(2)SO(4)] and [UO(2)(CH(3)CO(2))(2).2H(2)O/N,N-dimethylethylenediamine/H(2)SO(4)] systems has been studied using composition space. Two new compounds were formed in each system; [N(2)C(5)H(14)](2)[UO(2)(SO(4))(3)] (USO-17) and [N(2)C(5)H(14)][UO(2)(H(2)O)(SO(4))(2)] (USO-18) contain homopiperazine, and [N(2)C(4)H(14)][UO(2)(SO(4))(2)] (USO-19) and [N(2)C(4)H(14)][(UO(2))(2)(H(2)O)(SO(4))(3)].H(2)O (USO-20) contain N,N-dimethylethylenediamine. The relative stability of the products from each system is dependent upon the reactant mole fractions in the initial reaction gel. Crystal data: USO-17, a = 14.4975(3) A, b = 11.9109(3) A, c = 13.0157(3) A, beta = 110.475(1) degrees, monoclinic, C2/c (No. 15), Z = 4; for USO-18, a = 7.6955(2) A, b = 11.7717(3) A, c = 14.7038(4) A, orthorhombic, P22(1)2(1) (No. 18), Z = 4; for USO-19, a = 9.3322(1) A, b = 9.7743(2) A, c = 13.8897(3) A, orthorhombic, P2(1)2(1)2(1) (No. 19), Z = 4; and for USO-20, a = 11.2460(2) A, b = 10.5387(2) A, c = 17.0432(3) A, beta = 92.9884(6) degrees, monoclinic, P2(1)/c (No. 14), Z = 4. |
| spellingShingle | Doran, M Norquist, A O'Hare, D Exploration of composition space in templated uranium sulfates. |
| title | Exploration of composition space in templated uranium sulfates. |
| title_full | Exploration of composition space in templated uranium sulfates. |
| title_fullStr | Exploration of composition space in templated uranium sulfates. |
| title_full_unstemmed | Exploration of composition space in templated uranium sulfates. |
| title_short | Exploration of composition space in templated uranium sulfates. |
| title_sort | exploration of composition space in templated uranium sulfates |
| work_keys_str_mv | AT doranm explorationofcompositionspaceintemplateduraniumsulfates AT norquista explorationofcompositionspaceintemplateduraniumsulfates AT ohared explorationofcompositionspaceintemplateduraniumsulfates |