Proton transfer in the catalytic cycle of NiFe hydrogenases: insight from vibrational spectroscopy
Catalysis of H2 production and oxidation reactions is critical in renewable energy systems based around H2 as a clean fuel, but the present reliance on platinum-based catalysts is not sustainable. In nature, H2 is oxidized at minimal overpotential and high turnover frequencies at [NiFe] catalytic si...
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| Fformat: | Journal article |
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American Chemical Society
2017
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