Lower-rim ferrocenyl substituted calixarenes: new electrochemical sensors for anions
New ferrocene substituted calix[4 and 5]arenes have been prepared and the crystal structure of a lower-rim substituted bis ferrocene calix[4]arene (7) has been elucidated. The respective ferrocene/ferrocenium redox-couples of compounds 6 (a calix[4]arene tetra ferrocene amide) and 8 (a calix[5]arene...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
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1998
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| _version_ | 1797069744787947520 |
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| author | Gale, P Chen, Z Drew, M Heath, J Beer, P |
| author_facet | Gale, P Chen, Z Drew, M Heath, J Beer, P |
| author_sort | Gale, P |
| collection | OXFORD |
| description | New ferrocene substituted calix[4 and 5]arenes have been prepared and the crystal structure of a lower-rim substituted bis ferrocene calix[4]arene (7) has been elucidated. The respective ferrocene/ferrocenium redox-couples of compounds 6 (a calix[4]arene tetra ferrocene amide) and 8 (a calix[5]arene pentaferrocene amide) are shown to be significantly cathodically perturbed in the presence of anions by up to 160 mV in the presence of dihydrogen phosphate. © 1998 Elsevier Science Ltd. All rights reserved. |
| first_indexed | 2024-03-06T22:28:59Z |
| format | Journal article |
| id | oxford-uuid:57a687e8-139b-4c16-9b77-9486e25b43fa |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T22:28:59Z |
| publishDate | 1998 |
| record_format | dspace |
| spelling | oxford-uuid:57a687e8-139b-4c16-9b77-9486e25b43fa2022-03-26T16:58:02ZLower-rim ferrocenyl substituted calixarenes: new electrochemical sensors for anionsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:57a687e8-139b-4c16-9b77-9486e25b43faEnglishSymplectic Elements at Oxford1998Gale, PChen, ZDrew, MHeath, JBeer, PNew ferrocene substituted calix[4 and 5]arenes have been prepared and the crystal structure of a lower-rim substituted bis ferrocene calix[4]arene (7) has been elucidated. The respective ferrocene/ferrocenium redox-couples of compounds 6 (a calix[4]arene tetra ferrocene amide) and 8 (a calix[5]arene pentaferrocene amide) are shown to be significantly cathodically perturbed in the presence of anions by up to 160 mV in the presence of dihydrogen phosphate. © 1998 Elsevier Science Ltd. All rights reserved. |
| spellingShingle | Gale, P Chen, Z Drew, M Heath, J Beer, P Lower-rim ferrocenyl substituted calixarenes: new electrochemical sensors for anions |
| title | Lower-rim ferrocenyl substituted calixarenes: new electrochemical sensors for anions |
| title_full | Lower-rim ferrocenyl substituted calixarenes: new electrochemical sensors for anions |
| title_fullStr | Lower-rim ferrocenyl substituted calixarenes: new electrochemical sensors for anions |
| title_full_unstemmed | Lower-rim ferrocenyl substituted calixarenes: new electrochemical sensors for anions |
| title_short | Lower-rim ferrocenyl substituted calixarenes: new electrochemical sensors for anions |
| title_sort | lower rim ferrocenyl substituted calixarenes new electrochemical sensors for anions |
| work_keys_str_mv | AT galep lowerrimferrocenylsubstitutedcalixarenesnewelectrochemicalsensorsforanions AT chenz lowerrimferrocenylsubstitutedcalixarenesnewelectrochemicalsensorsforanions AT drewm lowerrimferrocenylsubstitutedcalixarenesnewelectrochemicalsensorsforanions AT heathj lowerrimferrocenylsubstitutedcalixarenesnewelectrochemicalsensorsforanions AT beerp lowerrimferrocenylsubstitutedcalixarenesnewelectrochemicalsensorsforanions |