Titanium tert-butyl- and trimethylsilyl-imido complexes with monopendant arm triazacyclononane ligands.
Neutral and cationic titanium imido complexes (R = t-Bu or SiMe 3) with a triazacyclononane ligand bearing a monopendant arm have been synthesized. The structures of [Ti(NSiMe 3)(L 1)Cl] and [Ti(NBu t)(L...
Главные авторы: | , , , |
---|---|
Формат: | Journal article |
Язык: | English |
Опубликовано: |
2001
|
_version_ | 1826273512576253952 |
---|---|
author | Gardner, J Robson, D Rees, L Mountford, P |
author_facet | Gardner, J Robson, D Rees, L Mountford, P |
author_sort | Gardner, J |
collection | OXFORD |
description | Neutral and cationic titanium imido complexes (R = t-Bu or SiMe 3) with a triazacyclononane ligand bearing a monopendant arm have been synthesized. The structures of [Ti(NSiMe 3)(L 1)Cl] and [Ti(NBu t)(L 2)Cl]Cl are reported where HL 1 =1-(2-hydroxy-3,5-di-tert-butylbenzyl)-4,7-diisopropyl-1,4,7-tria zacyclononane and L 2 = 1-(2-pyridylmethyl)-4,7-diisopropyl-1,4,7-triazacyclononane. |
first_indexed | 2024-03-06T22:29:19Z |
format | Journal article |
id | oxford-uuid:57c22215-7c3a-4af5-bfdd-acb9be86c596 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-06T22:29:19Z |
publishDate | 2001 |
record_format | dspace |
spelling | oxford-uuid:57c22215-7c3a-4af5-bfdd-acb9be86c5962022-03-26T16:58:40ZTitanium tert-butyl- and trimethylsilyl-imido complexes with monopendant arm triazacyclononane ligands.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:57c22215-7c3a-4af5-bfdd-acb9be86c596EnglishSymplectic Elements at Oxford2001Gardner, JRobson, DRees, LMountford, PNeutral and cationic titanium imido complexes (R = t-Bu or SiMe 3) with a triazacyclononane ligand bearing a monopendant arm have been synthesized. The structures of [Ti(NSiMe 3)(L 1)Cl] and [Ti(NBu t)(L 2)Cl]Cl are reported where HL 1 =1-(2-hydroxy-3,5-di-tert-butylbenzyl)-4,7-diisopropyl-1,4,7-tria zacyclononane and L 2 = 1-(2-pyridylmethyl)-4,7-diisopropyl-1,4,7-triazacyclononane. |
spellingShingle | Gardner, J Robson, D Rees, L Mountford, P Titanium tert-butyl- and trimethylsilyl-imido complexes with monopendant arm triazacyclononane ligands. |
title | Titanium tert-butyl- and trimethylsilyl-imido complexes with monopendant arm triazacyclononane ligands. |
title_full | Titanium tert-butyl- and trimethylsilyl-imido complexes with monopendant arm triazacyclononane ligands. |
title_fullStr | Titanium tert-butyl- and trimethylsilyl-imido complexes with monopendant arm triazacyclononane ligands. |
title_full_unstemmed | Titanium tert-butyl- and trimethylsilyl-imido complexes with monopendant arm triazacyclononane ligands. |
title_short | Titanium tert-butyl- and trimethylsilyl-imido complexes with monopendant arm triazacyclononane ligands. |
title_sort | titanium tert butyl and trimethylsilyl imido complexes with monopendant arm triazacyclononane ligands |
work_keys_str_mv | AT gardnerj titaniumtertbutylandtrimethylsilylimidocomplexeswithmonopendantarmtriazacyclononaneligands AT robsond titaniumtertbutylandtrimethylsilylimidocomplexeswithmonopendantarmtriazacyclononaneligands AT reesl titaniumtertbutylandtrimethylsilylimidocomplexeswithmonopendantarmtriazacyclononaneligands AT mountfordp titaniumtertbutylandtrimethylsilylimidocomplexeswithmonopendantarmtriazacyclononaneligands |