Titanium tert-butyl- and trimethylsilyl-imido complexes with monopendant arm triazacyclononane ligands.

Neutral and cationic titanium imido complexes (R = t-Bu or SiMe 3) with a triazacyclononane ligand bearing a monopendant arm have been synthesized. The structures of [Ti(NSiMe 3)(L 1)Cl] and [Ti(NBu t)(L...

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Главные авторы: Gardner, J, Robson, D, Rees, L, Mountford, P
Формат: Journal article
Язык:English
Опубликовано: 2001
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author Gardner, J
Robson, D
Rees, L
Mountford, P
author_facet Gardner, J
Robson, D
Rees, L
Mountford, P
author_sort Gardner, J
collection OXFORD
description Neutral and cationic titanium imido complexes (R = t-Bu or SiMe 3) with a triazacyclononane ligand bearing a monopendant arm have been synthesized. The structures of [Ti(NSiMe 3)(L 1)Cl] and [Ti(NBu t)(L 2)Cl]Cl are reported where HL 1 =1-(2-hydroxy-3,5-di-tert-butylbenzyl)-4,7-diisopropyl-1,4,7-tria zacyclononane and L 2 = 1-(2-pyridylmethyl)-4,7-diisopropyl-1,4,7-triazacyclononane.
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spelling oxford-uuid:57c22215-7c3a-4af5-bfdd-acb9be86c5962022-03-26T16:58:40ZTitanium tert-butyl- and trimethylsilyl-imido complexes with monopendant arm triazacyclononane ligands.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:57c22215-7c3a-4af5-bfdd-acb9be86c596EnglishSymplectic Elements at Oxford2001Gardner, JRobson, DRees, LMountford, PNeutral and cationic titanium imido complexes (R = t-Bu or SiMe 3) with a triazacyclononane ligand bearing a monopendant arm have been synthesized. The structures of [Ti(NSiMe 3)(L 1)Cl] and [Ti(NBu t)(L 2)Cl]Cl are reported where HL 1 =1-(2-hydroxy-3,5-di-tert-butylbenzyl)-4,7-diisopropyl-1,4,7-tria zacyclononane and L 2 = 1-(2-pyridylmethyl)-4,7-diisopropyl-1,4,7-triazacyclononane.
spellingShingle Gardner, J
Robson, D
Rees, L
Mountford, P
Titanium tert-butyl- and trimethylsilyl-imido complexes with monopendant arm triazacyclononane ligands.
title Titanium tert-butyl- and trimethylsilyl-imido complexes with monopendant arm triazacyclononane ligands.
title_full Titanium tert-butyl- and trimethylsilyl-imido complexes with monopendant arm triazacyclononane ligands.
title_fullStr Titanium tert-butyl- and trimethylsilyl-imido complexes with monopendant arm triazacyclononane ligands.
title_full_unstemmed Titanium tert-butyl- and trimethylsilyl-imido complexes with monopendant arm triazacyclononane ligands.
title_short Titanium tert-butyl- and trimethylsilyl-imido complexes with monopendant arm triazacyclononane ligands.
title_sort titanium tert butyl and trimethylsilyl imido complexes with monopendant arm triazacyclononane ligands
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AT robsond titaniumtertbutylandtrimethylsilylimidocomplexeswithmonopendantarmtriazacyclononaneligands
AT reesl titaniumtertbutylandtrimethylsilylimidocomplexeswithmonopendantarmtriazacyclononaneligands
AT mountfordp titaniumtertbutylandtrimethylsilylimidocomplexeswithmonopendantarmtriazacyclononaneligands