Ligand effects in the organolithium-mediated enantioselective alpha-deprotonation of achiral epoxides

The enantioselective α-deprotonation-rearrangement of achiral epoxides using organolithiums with C2-symmetric ligands [bisoxazolines 4a-d and (-)-α-isosparteine 5] is described.

Bibliografische gegevens
Hoofdauteurs: Hodgson, D, Lee, G
Formaat: Journal article
Taal:English
Gepubliceerd in: 1997
Omschrijving
Samenvatting:The enantioselective α-deprotonation-rearrangement of achiral epoxides using organolithiums with C2-symmetric ligands [bisoxazolines 4a-d and (-)-α-isosparteine 5] is described.