DABSO-based, three-component, one-pot sulfone synthesis.
The addition of Grignard reagents or organolithium reagents to the SO2-surrogate DABSO generates a diverse set of metal sulfinates, suitable for direct conversion to sulfone products. The metal sulfinates can be trapped in situ with a wide range of C-electrophiles, including alkyl, allyl, and benzyl...
| Príomhchruthaitheoirí: | , , , |
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| Formáid: | Journal article |
| Teanga: | English |
| Foilsithe / Cruthaithe: |
American Chemical Society
2013
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| _version_ | 1826273606260228096 |
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| author | Deeming, A Russell, C Hennessy, A Willis, M |
| author_facet | Deeming, A Russell, C Hennessy, A Willis, M |
| author_sort | Deeming, A |
| collection | OXFORD |
| description | The addition of Grignard reagents or organolithium reagents to the SO2-surrogate DABSO generates a diverse set of metal sulfinates, suitable for direct conversion to sulfone products. The metal sulfinates can be trapped in situ with a wide range of C-electrophiles, including alkyl, allyl, and benzyl halides, epoxides, and (hetero)aryliodoniums. |
| first_indexed | 2024-03-06T22:30:45Z |
| format | Journal article |
| id | oxford-uuid:58324890-5cff-4d41-bc8c-ac98e7afb76c |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T22:30:45Z |
| publishDate | 2013 |
| publisher | American Chemical Society |
| record_format | dspace |
| spelling | oxford-uuid:58324890-5cff-4d41-bc8c-ac98e7afb76c2022-03-26T17:01:40ZDABSO-based, three-component, one-pot sulfone synthesis.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:58324890-5cff-4d41-bc8c-ac98e7afb76cEnglishSymplectic Elements at OxfordAmerican Chemical Society2013Deeming, ARussell, CHennessy, AWillis, MThe addition of Grignard reagents or organolithium reagents to the SO2-surrogate DABSO generates a diverse set of metal sulfinates, suitable for direct conversion to sulfone products. The metal sulfinates can be trapped in situ with a wide range of C-electrophiles, including alkyl, allyl, and benzyl halides, epoxides, and (hetero)aryliodoniums. |
| spellingShingle | Deeming, A Russell, C Hennessy, A Willis, M DABSO-based, three-component, one-pot sulfone synthesis. |
| title | DABSO-based, three-component, one-pot sulfone synthesis. |
| title_full | DABSO-based, three-component, one-pot sulfone synthesis. |
| title_fullStr | DABSO-based, three-component, one-pot sulfone synthesis. |
| title_full_unstemmed | DABSO-based, three-component, one-pot sulfone synthesis. |
| title_short | DABSO-based, three-component, one-pot sulfone synthesis. |
| title_sort | dabso based three component one pot sulfone synthesis |
| work_keys_str_mv | AT deeminga dabsobasedthreecomponentonepotsulfonesynthesis AT russellc dabsobasedthreecomponentonepotsulfonesynthesis AT hennessya dabsobasedthreecomponentonepotsulfonesynthesis AT willism dabsobasedthreecomponentonepotsulfonesynthesis |