Reductive cyclotrimerization of carbon monoxide to the deltate dianion by an organometallic uranium complex.
Despite the long history of the Fischer-Tropsch reaction, carbon monoxide has proven remarkably resistant to selective homologation under mild conditions. Here, we find that an organouranium(III) complex induces efficient reductive trimerization of carbon monoxide at room temperature and pressure. T...
Автори: | Summerscales, O, Cloke, F, Hitchcock, P, Green, J, Hazari, N |
---|---|
Формат: | Journal article |
Мова: | English |
Опубліковано: |
2006
|
Схожі ресурси
Схожі ресурси
-
Selective reduction and homologation of carbon monoxide by organometallic iron complexes
за авторством: Helen R. Sharpe, та інші
Опубліковано: (2018-09-01) -
The hexamethylpentalene dianion and other reagents for organometallic pentalene chemistry.
за авторством: Ashley, A, та інші
Опубліковано: (2007) -
Reductive cyclotetramerization of CO to squarate by a U(III) complex: the X-ray crystal structure of [(U (eta-C8H6{SiiPr3-1,4}2)(eta-C5Me4H)]2(mu-eta2: eta2-C4O4).
за авторством: Summerscales, O, та інші
Опубліковано: (2006) -
The organometallic chemistry of ambident aceton dianions : reactions with Group 4 and 14 element dihalides
за авторством: Wang, Tao
Опубліковано: (2007) -
Controlled Release of Carbon Monoxide from a Pseudo Electron-Deficient Organometallic Complex
за авторством: Anaïs Pitto-Barry, та інші
Опубліковано: (2018-11-01)