Electronic band structure of carbon nanomaterials

<p>This thesis reports the study of electronic structures for single-walled carbon nanotubes, single layer graphene and thin graphite. A brief introduction is given in Chapter 1 for the geometric and electronic structures of the materials studied while a review for the theory and experimental...

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Main Author: Chuang, KC
Other Authors: Nicholas, RJ
Format: Thesis
Language:English
Published: 2009
Subjects:
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author Chuang, KC
author2 Nicholas, RJ
author_facet Nicholas, RJ
Chuang, KC
author_sort Chuang, KC
collection OXFORD
description <p>This thesis reports the study of electronic structures for single-walled carbon nanotubes, single layer graphene and thin graphite. A brief introduction is given in Chapter 1 for the geometric and electronic structures of the materials studied while a review for the theory and experimental results relevant to this thesis is given in Chapter 2.</p> <p>The effects of hydrostatic pressure on surfactant-wrapped-single walled carbon nanotubes are studied in Chapter 3 by using photoluminscence and photoluminscence excitation mapping. It is found that the changes to the optical properties can be explained by the compression in carbon-carbon bonds, an effective uniaxial strain exerted on the nanotubes and changes in the surrounding environment leading to changes in the many-body interactions experienced by the nanotubes. Chapter 4 reports the study of cross-polarized photoluminescence of nanotubes isolated by conjugated polymers dispersed in solvents. The effects of Coulomb interactions on the optical bandgaps of the nanotubes are discussed here.</p> <p>Chapter 5 reports Cyclotron resonances studies of graphene monolayers. It is found that a significant asymmetry exists between the electron and hole band structures near the Dirac point, and the asymmetry is bigger than that is expected in a simple tight-binding model. Chapter 6 reports a magnetoabsorption study of the electronic structures near the <em>K</em>- and <em>H</em>- points. It is found that the transitions are not describe well by the conventional Slonczewski-Weiss-McClure model, but can be described instead with a simplified asymmetric effective bilayer model.</p>
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spelling oxford-uuid:590ccfa7-2737-40c4-9a9c-ddb1b710cfef2022-03-26T17:07:30ZElectronic band structure of carbon nanomaterialsThesishttp://purl.org/coar/resource_type/c_db06uuid:590ccfa7-2737-40c4-9a9c-ddb1b710cfefPhysicsCondensed matter theoryPhysical SciencesEnglishOxford University Research Archive - Valet2009Chuang, KCNicholas, RJ<p>This thesis reports the study of electronic structures for single-walled carbon nanotubes, single layer graphene and thin graphite. A brief introduction is given in Chapter 1 for the geometric and electronic structures of the materials studied while a review for the theory and experimental results relevant to this thesis is given in Chapter 2.</p> <p>The effects of hydrostatic pressure on surfactant-wrapped-single walled carbon nanotubes are studied in Chapter 3 by using photoluminscence and photoluminscence excitation mapping. It is found that the changes to the optical properties can be explained by the compression in carbon-carbon bonds, an effective uniaxial strain exerted on the nanotubes and changes in the surrounding environment leading to changes in the many-body interactions experienced by the nanotubes. Chapter 4 reports the study of cross-polarized photoluminescence of nanotubes isolated by conjugated polymers dispersed in solvents. The effects of Coulomb interactions on the optical bandgaps of the nanotubes are discussed here.</p> <p>Chapter 5 reports Cyclotron resonances studies of graphene monolayers. It is found that a significant asymmetry exists between the electron and hole band structures near the Dirac point, and the asymmetry is bigger than that is expected in a simple tight-binding model. Chapter 6 reports a magnetoabsorption study of the electronic structures near the <em>K</em>- and <em>H</em>- points. It is found that the transitions are not describe well by the conventional Slonczewski-Weiss-McClure model, but can be described instead with a simplified asymmetric effective bilayer model.</p>
spellingShingle Physics
Condensed matter theory
Physical Sciences
Chuang, KC
Electronic band structure of carbon nanomaterials
title Electronic band structure of carbon nanomaterials
title_full Electronic band structure of carbon nanomaterials
title_fullStr Electronic band structure of carbon nanomaterials
title_full_unstemmed Electronic band structure of carbon nanomaterials
title_short Electronic band structure of carbon nanomaterials
title_sort electronic band structure of carbon nanomaterials
topic Physics
Condensed matter theory
Physical Sciences
work_keys_str_mv AT chuangkc electronicbandstructureofcarbonnanomaterials