Neutral color semitransparent microstructured perovskite solar cells.

Neutral-colored semitransparent solar cells are commercially desired to integrate solar cells into the windows and cladding of buildings and automotive applications. Here, we report the use of morphological control of perovskite thin films to form semitransparent planar heterojunction solar cells wi...

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Główni autorzy: Eperon, G, Burlakov, V, Goriely, A, Snaith, H
Format: Journal article
Język:English
Wydane: American Chemical Society 2013
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author Eperon, G
Burlakov, V
Goriely, A
Snaith, H
author_facet Eperon, G
Burlakov, V
Goriely, A
Snaith, H
author_sort Eperon, G
collection OXFORD
description Neutral-colored semitransparent solar cells are commercially desired to integrate solar cells into the windows and cladding of buildings and automotive applications. Here, we report the use of morphological control of perovskite thin films to form semitransparent planar heterojunction solar cells with neutral color and comparatively high efficiencies. We take advantage of spontaneous dewetting to create microstructured arrays of perovskite "islands", on a length-scale small enough to appear continuous to the eye yet large enough to enable unattenuated transmission of light between the islands. The islands are thick enough to absorb most visible light, and the combination of completely absorbing and completely transparent regions results in neutral transmission of light. Using these films, we fabricate thin-film solar cells with respectable power conversion efficiencies. Remarkably, we find that such discontinuous films still have good rectification behavior and relatively high open-circuit voltages due to the inherent rectification between the n- and p-type charge collection layers. Furthermore, we demonstrate the ease of "color-tinting" such microstructured perovksite solar cells with no reduction in performance, by incorporation of a dye within the hole transport medium.
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spelling oxford-uuid:5934122b-9c39-4d11-879f-c28b909ae1572022-03-26T17:08:23ZNeutral color semitransparent microstructured perovskite solar cells.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:5934122b-9c39-4d11-879f-c28b909ae157EnglishSymplectic Elements at OxfordAmerican Chemical Society2013Eperon, GBurlakov, VGoriely, ASnaith, HNeutral-colored semitransparent solar cells are commercially desired to integrate solar cells into the windows and cladding of buildings and automotive applications. Here, we report the use of morphological control of perovskite thin films to form semitransparent planar heterojunction solar cells with neutral color and comparatively high efficiencies. We take advantage of spontaneous dewetting to create microstructured arrays of perovskite "islands", on a length-scale small enough to appear continuous to the eye yet large enough to enable unattenuated transmission of light between the islands. The islands are thick enough to absorb most visible light, and the combination of completely absorbing and completely transparent regions results in neutral transmission of light. Using these films, we fabricate thin-film solar cells with respectable power conversion efficiencies. Remarkably, we find that such discontinuous films still have good rectification behavior and relatively high open-circuit voltages due to the inherent rectification between the n- and p-type charge collection layers. Furthermore, we demonstrate the ease of "color-tinting" such microstructured perovksite solar cells with no reduction in performance, by incorporation of a dye within the hole transport medium.
spellingShingle Eperon, G
Burlakov, V
Goriely, A
Snaith, H
Neutral color semitransparent microstructured perovskite solar cells.
title Neutral color semitransparent microstructured perovskite solar cells.
title_full Neutral color semitransparent microstructured perovskite solar cells.
title_fullStr Neutral color semitransparent microstructured perovskite solar cells.
title_full_unstemmed Neutral color semitransparent microstructured perovskite solar cells.
title_short Neutral color semitransparent microstructured perovskite solar cells.
title_sort neutral color semitransparent microstructured perovskite solar cells
work_keys_str_mv AT eperong neutralcolorsemitransparentmicrostructuredperovskitesolarcells
AT burlakovv neutralcolorsemitransparentmicrostructuredperovskitesolarcells
AT gorielya neutralcolorsemitransparentmicrostructuredperovskitesolarcells
AT snaithh neutralcolorsemitransparentmicrostructuredperovskitesolarcells