Influence of cyclodextrin size on fluorescence quenching in conjugated polyrotaxanes by methyl viologen in aqueous solution

Poly(4,4′-diphenylenevinylene) rotaxanes and [2]rotaxanes with α-, β-, γ-cyclodextrin macrocycles were synthesised and their sensitivities to fluorescence quenching by methyl viologen in aqueous solution were determined, relative to uninsulated analogues. Stern-Volmer analysis revealed that the fluo...

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Autors principals: Oddy, F, Brovelli, S, Stone, M, Klotz, E, Cacialli, F, Anderson, H
Format: Journal article
Idioma:English
Publicat: 2009