Impedance voltammetry of electro-dimerization mechanisms: Application to the reduction of the methyl viologen di-cation at mercury electrodes and aqueous solutions
The faradaic impedance for an electrode mechanism with a reversible homogeneous dimerization reaction following the electron transfer step is derived. The chemical reaction shows up in the frequency dependence of the faradaic impedance and admittance in a similar way as deduced by Sluyters-Rehbach a...
| Hauptverfasser: | , , , |
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| Format: | Journal article |
| Sprache: | English |
| Veröffentlicht: |
1998
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