Impedance voltammetry of electro-dimerization mechanisms: Application to the reduction of the methyl viologen di-cation at mercury electrodes and aqueous solutions
The faradaic impedance for an electrode mechanism with a reversible homogeneous dimerization reaction following the electron transfer step is derived. The chemical reaction shows up in the frequency dependence of the faradaic impedance and admittance in a similar way as deduced by Sluyters-Rehbach a...
| Auteurs principaux: | , , , |
|---|---|
| Format: | Journal article |
| Langue: | English |
| Publié: |
1998
|