Recent developments in the non-cyclopentadienyl organometallic and related chemistry of scandium.

Up to the early to mid 1990s the organometallic chemistry of scandium was dominated by cyclopentadienyl derivatives. This present article highlights advances in the synthesis and reactivity of non-cyclopentadienyl organometallic and related compounds of scandium. These include: compounds containing...

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Main Authors: Mountford, P, Ward, B
Format: Journal article
Language:English
Published: 2003
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author Mountford, P
Ward, B
author_facet Mountford, P
Ward, B
author_sort Mountford, P
collection OXFORD
description Up to the early to mid 1990s the organometallic chemistry of scandium was dominated by cyclopentadienyl derivatives. This present article highlights advances in the synthesis and reactivity of non-cyclopentadienyl organometallic and related compounds of scandium. These include: compounds containing arene and other eta(x)-CxRx ligands; compounds with macrocyclic and fac-L3 ligands; compounds with polydentate ligands that incorporate amide donors; compounds with bidentate, monoanionic N,N' donor ligands; and compounds with iminophenolate, bis(phenoxide) and some other anionic O-donor ligands.
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spelling oxford-uuid:5a38ba8b-d5bd-4962-a4ed-fc41668eb6822022-03-26T17:14:31ZRecent developments in the non-cyclopentadienyl organometallic and related chemistry of scandium.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:5a38ba8b-d5bd-4962-a4ed-fc41668eb682EnglishSymplectic Elements at Oxford2003Mountford, PWard, BUp to the early to mid 1990s the organometallic chemistry of scandium was dominated by cyclopentadienyl derivatives. This present article highlights advances in the synthesis and reactivity of non-cyclopentadienyl organometallic and related compounds of scandium. These include: compounds containing arene and other eta(x)-CxRx ligands; compounds with macrocyclic and fac-L3 ligands; compounds with polydentate ligands that incorporate amide donors; compounds with bidentate, monoanionic N,N' donor ligands; and compounds with iminophenolate, bis(phenoxide) and some other anionic O-donor ligands.
spellingShingle Mountford, P
Ward, B
Recent developments in the non-cyclopentadienyl organometallic and related chemistry of scandium.
title Recent developments in the non-cyclopentadienyl organometallic and related chemistry of scandium.
title_full Recent developments in the non-cyclopentadienyl organometallic and related chemistry of scandium.
title_fullStr Recent developments in the non-cyclopentadienyl organometallic and related chemistry of scandium.
title_full_unstemmed Recent developments in the non-cyclopentadienyl organometallic and related chemistry of scandium.
title_short Recent developments in the non-cyclopentadienyl organometallic and related chemistry of scandium.
title_sort recent developments in the non cyclopentadienyl organometallic and related chemistry of scandium
work_keys_str_mv AT mountfordp recentdevelopmentsinthenoncyclopentadienylorganometallicandrelatedchemistryofscandium
AT wardb recentdevelopmentsinthenoncyclopentadienylorganometallicandrelatedchemistryofscandium