A scaling law for distinct electrocaloric cooling performance in low-dimensional organic, relaxor and anti-ferroelectrics
Electrocaloric (EC) materials show promise in eco-friendly solid-state refrigeration and integrable on-chip thermal management. While direct measurement of EC thin-films still remains challenging, a generic theoretical framework for quantifying the cooling properties of rich EC materials including n...
Main Authors: | , , , , , |
---|---|
Format: | Journal article |
Language: | English |
Published: |
Springer Nature
2017
|
_version_ | 1797070352195518464 |
---|---|
author | Shi, Y Huang, L Soh, A Weng, G Liu, S Redfern, S |
author_facet | Shi, Y Huang, L Soh, A Weng, G Liu, S Redfern, S |
author_sort | Shi, Y |
collection | OXFORD |
description | Electrocaloric (EC) materials show promise in eco-friendly solid-state refrigeration and integrable on-chip thermal management. While direct measurement of EC thin-films still remains challenging, a generic theoretical framework for quantifying the cooling properties of rich EC materials including normal-, relaxor-, organic- and anti-ferroelectrics is imperative for exploiting new flexible and room-temperature cooling alternatives. Here, we present a versatile theory that combines Master equation with Maxwell relations and analytically relates the macroscopic cooling responses in EC materials with the intrinsic diffuseness of phase transitions and correlation characteristics. Under increased electric fields, both EC entropy and adiabatic temperature changes increase quadratically initially, followed by further linear growth and eventual gradual saturation. The upper bound of entropy change (∆Smax) is limited by distinct correlation volumes (V cr ) and transition diffuseness. The linearity between V cr and the transition diffuseness is emphasized, while ∆Smax = 300 kJ/(K.m3) is obtained for Pb0.8Ba0.2ZrO3. The ∆Smax in antiferroelectric Pb0.95Zr0.05TiO3, Pb0.8Ba0.2ZrO3 and polymeric ferroelectrics scales proportionally with V cr −2.2, owing to the one-dimensional structural constraint on lattice-scale depolarization dynamics; whereas ∆Smax in relaxor and normal ferroelectrics scales as ∆Smax ~ V cr −0.37, which tallies with a dipolar interaction exponent of 2/3 in EC materials and the well-proven fractional dimensionality of 2.5 for ferroelectric domain walls. |
first_indexed | 2024-03-06T22:37:36Z |
format | Journal article |
id | oxford-uuid:5a709f0a-e7ef-4cab-876f-3657063cc1e9 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-06T22:37:36Z |
publishDate | 2017 |
publisher | Springer Nature |
record_format | dspace |
spelling | oxford-uuid:5a709f0a-e7ef-4cab-876f-3657063cc1e92022-03-26T17:15:47ZA scaling law for distinct electrocaloric cooling performance in low-dimensional organic, relaxor and anti-ferroelectricsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:5a709f0a-e7ef-4cab-876f-3657063cc1e9EnglishSymplectic Elements at OxfordSpringer Nature2017Shi, YHuang, LSoh, AWeng, GLiu, SRedfern, SElectrocaloric (EC) materials show promise in eco-friendly solid-state refrigeration and integrable on-chip thermal management. While direct measurement of EC thin-films still remains challenging, a generic theoretical framework for quantifying the cooling properties of rich EC materials including normal-, relaxor-, organic- and anti-ferroelectrics is imperative for exploiting new flexible and room-temperature cooling alternatives. Here, we present a versatile theory that combines Master equation with Maxwell relations and analytically relates the macroscopic cooling responses in EC materials with the intrinsic diffuseness of phase transitions and correlation characteristics. Under increased electric fields, both EC entropy and adiabatic temperature changes increase quadratically initially, followed by further linear growth and eventual gradual saturation. The upper bound of entropy change (∆Smax) is limited by distinct correlation volumes (V cr ) and transition diffuseness. The linearity between V cr and the transition diffuseness is emphasized, while ∆Smax = 300 kJ/(K.m3) is obtained for Pb0.8Ba0.2ZrO3. The ∆Smax in antiferroelectric Pb0.95Zr0.05TiO3, Pb0.8Ba0.2ZrO3 and polymeric ferroelectrics scales proportionally with V cr −2.2, owing to the one-dimensional structural constraint on lattice-scale depolarization dynamics; whereas ∆Smax in relaxor and normal ferroelectrics scales as ∆Smax ~ V cr −0.37, which tallies with a dipolar interaction exponent of 2/3 in EC materials and the well-proven fractional dimensionality of 2.5 for ferroelectric domain walls. |
spellingShingle | Shi, Y Huang, L Soh, A Weng, G Liu, S Redfern, S A scaling law for distinct electrocaloric cooling performance in low-dimensional organic, relaxor and anti-ferroelectrics |
title | A scaling law for distinct electrocaloric cooling performance in low-dimensional organic, relaxor and anti-ferroelectrics |
title_full | A scaling law for distinct electrocaloric cooling performance in low-dimensional organic, relaxor and anti-ferroelectrics |
title_fullStr | A scaling law for distinct electrocaloric cooling performance in low-dimensional organic, relaxor and anti-ferroelectrics |
title_full_unstemmed | A scaling law for distinct electrocaloric cooling performance in low-dimensional organic, relaxor and anti-ferroelectrics |
title_short | A scaling law for distinct electrocaloric cooling performance in low-dimensional organic, relaxor and anti-ferroelectrics |
title_sort | scaling law for distinct electrocaloric cooling performance in low dimensional organic relaxor and anti ferroelectrics |
work_keys_str_mv | AT shiy ascalinglawfordistinctelectrocaloriccoolingperformanceinlowdimensionalorganicrelaxorandantiferroelectrics AT huangl ascalinglawfordistinctelectrocaloriccoolingperformanceinlowdimensionalorganicrelaxorandantiferroelectrics AT soha ascalinglawfordistinctelectrocaloriccoolingperformanceinlowdimensionalorganicrelaxorandantiferroelectrics AT wengg ascalinglawfordistinctelectrocaloriccoolingperformanceinlowdimensionalorganicrelaxorandantiferroelectrics AT lius ascalinglawfordistinctelectrocaloriccoolingperformanceinlowdimensionalorganicrelaxorandantiferroelectrics AT redferns ascalinglawfordistinctelectrocaloriccoolingperformanceinlowdimensionalorganicrelaxorandantiferroelectrics AT shiy scalinglawfordistinctelectrocaloriccoolingperformanceinlowdimensionalorganicrelaxorandantiferroelectrics AT huangl scalinglawfordistinctelectrocaloriccoolingperformanceinlowdimensionalorganicrelaxorandantiferroelectrics AT soha scalinglawfordistinctelectrocaloriccoolingperformanceinlowdimensionalorganicrelaxorandantiferroelectrics AT wengg scalinglawfordistinctelectrocaloriccoolingperformanceinlowdimensionalorganicrelaxorandantiferroelectrics AT lius scalinglawfordistinctelectrocaloriccoolingperformanceinlowdimensionalorganicrelaxorandantiferroelectrics AT redferns scalinglawfordistinctelectrocaloriccoolingperformanceinlowdimensionalorganicrelaxorandantiferroelectrics |