ALPHA-ALKENYLATION OF BETA-DICARBONYL COMPOUNDS WITH ALK-1-ENYL-LEAD TRIACETATES
Addition of lead tetra-acetate to a chloroform solution of a dialk-1-enylmercury or an alk-1-enyltributylstannane results in rapid formation of a relatively unstable species, believed to be an alk-1-enyl-lead triacetate, which can be used for the α-alkenylation of β-dicarbonyl compounds.
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1984
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| _version_ | 1797070381953056768 |
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| author | Moloney, M Pinhey, J |
| author_facet | Moloney, M Pinhey, J |
| author_sort | Moloney, M |
| collection | OXFORD |
| description | Addition of lead tetra-acetate to a chloroform solution of a dialk-1-enylmercury or an alk-1-enyltributylstannane results in rapid formation of a relatively unstable species, believed to be an alk-1-enyl-lead triacetate, which can be used for the α-alkenylation of β-dicarbonyl compounds. |
| first_indexed | 2024-03-06T22:38:00Z |
| format | Journal article |
| id | oxford-uuid:5a95886e-131e-4e72-b416-96bd8e8a773a |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T22:38:00Z |
| publishDate | 1984 |
| record_format | dspace |
| spelling | oxford-uuid:5a95886e-131e-4e72-b416-96bd8e8a773a2022-03-26T17:16:34ZALPHA-ALKENYLATION OF BETA-DICARBONYL COMPOUNDS WITH ALK-1-ENYL-LEAD TRIACETATESJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:5a95886e-131e-4e72-b416-96bd8e8a773aEnglishSymplectic Elements at Oxford1984Moloney, MPinhey, JAddition of lead tetra-acetate to a chloroform solution of a dialk-1-enylmercury or an alk-1-enyltributylstannane results in rapid formation of a relatively unstable species, believed to be an alk-1-enyl-lead triacetate, which can be used for the α-alkenylation of β-dicarbonyl compounds. |
| spellingShingle | Moloney, M Pinhey, J ALPHA-ALKENYLATION OF BETA-DICARBONYL COMPOUNDS WITH ALK-1-ENYL-LEAD TRIACETATES |
| title | ALPHA-ALKENYLATION OF BETA-DICARBONYL COMPOUNDS WITH ALK-1-ENYL-LEAD TRIACETATES |
| title_full | ALPHA-ALKENYLATION OF BETA-DICARBONYL COMPOUNDS WITH ALK-1-ENYL-LEAD TRIACETATES |
| title_fullStr | ALPHA-ALKENYLATION OF BETA-DICARBONYL COMPOUNDS WITH ALK-1-ENYL-LEAD TRIACETATES |
| title_full_unstemmed | ALPHA-ALKENYLATION OF BETA-DICARBONYL COMPOUNDS WITH ALK-1-ENYL-LEAD TRIACETATES |
| title_short | ALPHA-ALKENYLATION OF BETA-DICARBONYL COMPOUNDS WITH ALK-1-ENYL-LEAD TRIACETATES |
| title_sort | alpha alkenylation of beta dicarbonyl compounds with alk 1 enyl lead triacetates |
| work_keys_str_mv | AT moloneym alphaalkenylationofbetadicarbonylcompoundswithalk1enylleadtriacetates AT pinheyj alphaalkenylationofbetadicarbonylcompoundswithalk1enylleadtriacetates |