A first transition series pseudotetrahedral oxynitride anion: synthesis and characterization of Ba(2)VO(3)N.
Ammonolysis of reactive oxide precursors affords the vanadium(V) phase Ba(2)VO(3)N that is shown by X-ray and neutron powder diffraction and Raman spectroscopy to contain pseudotetrahedral VO(3)N(4-) anions. This is the first example of such species for the first transition series metals.
Bibliographic Details
Main Authors: |
Clarke, S,
Chalker, P,
Holman, J,
Michie, C,
Puyet, M,
Rosseinsky, M |
Format: | Journal article
|
Language: | English |
Published: |
2002
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