Substrate scope and stereocontrol in the Rh(II)-catalysed oxyamination of allylic carbamates

Application of a modified Du Bois protocol for rhodium-stabilised nitrenoid generation to a variety of allylic carbamates results in 4-acetoxymethyl-1,3-oxazolidin-2-one derivatives with moderate to high levels of stereocontrol. © 2014 Elsevier Ltd. All rights reserved.

Bibliographic Details
Main Authors: Unsworth, W, Lamont, S, Robertson, J
Format: Journal article
Language:English
Published: 2014
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author Unsworth, W
Lamont, S
Robertson, J
author_facet Unsworth, W
Lamont, S
Robertson, J
author_sort Unsworth, W
collection OXFORD
description Application of a modified Du Bois protocol for rhodium-stabilised nitrenoid generation to a variety of allylic carbamates results in 4-acetoxymethyl-1,3-oxazolidin-2-one derivatives with moderate to high levels of stereocontrol. © 2014 Elsevier Ltd. All rights reserved.
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spelling oxford-uuid:5b53705c-105d-4479-830e-dd351fec574c2022-03-26T17:21:24ZSubstrate scope and stereocontrol in the Rh(II)-catalysed oxyamination of allylic carbamatesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:5b53705c-105d-4479-830e-dd351fec574cEnglishSymplectic Elements at Oxford2014Unsworth, WLamont, SRobertson, JApplication of a modified Du Bois protocol for rhodium-stabilised nitrenoid generation to a variety of allylic carbamates results in 4-acetoxymethyl-1,3-oxazolidin-2-one derivatives with moderate to high levels of stereocontrol. © 2014 Elsevier Ltd. All rights reserved.
spellingShingle Unsworth, W
Lamont, S
Robertson, J
Substrate scope and stereocontrol in the Rh(II)-catalysed oxyamination of allylic carbamates
title Substrate scope and stereocontrol in the Rh(II)-catalysed oxyamination of allylic carbamates
title_full Substrate scope and stereocontrol in the Rh(II)-catalysed oxyamination of allylic carbamates
title_fullStr Substrate scope and stereocontrol in the Rh(II)-catalysed oxyamination of allylic carbamates
title_full_unstemmed Substrate scope and stereocontrol in the Rh(II)-catalysed oxyamination of allylic carbamates
title_short Substrate scope and stereocontrol in the Rh(II)-catalysed oxyamination of allylic carbamates
title_sort substrate scope and stereocontrol in the rh ii catalysed oxyamination of allylic carbamates
work_keys_str_mv AT unsworthw substratescopeandstereocontrolintherhiicatalysedoxyaminationofallyliccarbamates
AT lamonts substratescopeandstereocontrolintherhiicatalysedoxyaminationofallyliccarbamates
AT robertsonj substratescopeandstereocontrolintherhiicatalysedoxyaminationofallyliccarbamates