Substrate scope and stereocontrol in the Rh(II)-catalysed oxyamination of allylic carbamates

Application of a modified Du Bois protocol for rhodium-stabilised nitrenoid generation to a variety of allylic carbamates results in 4-acetoxymethyl-1,3-oxazolidin-2-one derivatives with moderate to high levels of stereocontrol. © 2014 Elsevier Ltd. All rights reserved.

Bibliographic Details
Main Authors: Unsworth, W, Lamont, S, Robertson, J
Format: Journal article
Language:English
Published: 2014