| 要約: | Specific-heat and magnetic-susceptibility measurements are reported for the polycrystalline spinel compounds GeNi2 O4 and GeCo2 O4 in magnetic fields up to 14 T and 0.5 K≤T≤400 K. Both compounds have first-order antiferromagnetic transitions. There are two sharp closely spaced magnetic-ordering anomalies for GeNi2 O4 at Néel temperatures TN1 (0) =12.080 K and TN2 (0) =11.433 K in zero magnetic field. There is also a broad anomaly in the specific heat centered at ∼5 K, which is present for all fields. Spin waves with an average gap of 10.9 K are associated with this anomaly, which is confirmed by neutron-scattering measurements. An unusual feature of the antiferromagnetism for GeNi2 O4 is the simultaneous presence of both gapped and ungapped spin waves in the Néel state, inferred from the specific-heat data. GeCo2 O4 has a single anomaly at TN (0) =20.617 K in zero magnetic field. Spin waves with an average gap of 38.7 K are derived from fitting the low-temperature specific heat and are also observed by neutron scattering. For both compounds ∼50% of the derived magnetic entropy is below the ordering temperatures, and the total magnetic entropies are only ∼60% of that predicted for the Ni2+ and Co2+ single-ion ground-state configurations. The missing entropy is not linked to magnetic disorder in the ground state or hidden ordering below 0.5 K. It is postulated that the missing entropy is accounted for by the presence of substantial magnetic correlations well above the Néel temperatures. Fitting the GeNi2 O4 susceptibilities to the Curie-Weiss law yields parameters that are consistent with those found for Ni2+ ions in a crystal-electric-field environment including octahedral and trigonal components. The application of the Curie-Weiss law to the GeCo2 O4 susceptibilities is not valid because of low-lying crystal-electric-field states. © 2008 The American Physical Society.
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