Origins of stereoselectivity in the trans Diels-Alder paradigm.

Origins of stereoselectivity in the trans Diels-Alder paradigm.

The regioselectivity and stereoselectivity aspects of the Diels-Alder/radical hydrodenitration reaction sequence leading to trans-fused ring systems have been investigated with density functional calculations. A continuum of transition structures representing Diels-Alder and hetero-Diels-Alder cyclo...

Full description

Bibliographic Details
Main Authors:	Paton, R, Mackey, J, Kim, W, Lee, J, Danishefsky, S, Houk, K
Format:	Journal article
Language:	English
Published:	2010

Similar Items

Intramolecular Diels-Alder reactions of cycloalkenones: stereoselectivity, Lewis acid acceleration, and halogen substituent effects.
by: Pham, H, et al.
Published: (2014)

Experimental Diels-Alder reactivities of cycloalkenones and cyclic dienes explained through transition-state distortion energies.
by: Paton, R, et al.
Published: (2011)

Dynamic intermediates in the radical cation diels–alder cycloaddition: lifetime and suprafacial stereoselectivity
by: Tan, J, et al.
Published: (2018)

Origins of regioselectivity of Diels-Alder reactions for the synthesis of bisanthraquinone antibiotic BE-43472B.
by: Hayden, A, et al.
Published: (2010)

Probing substituent effects in aryl-aryl interactions using stereoselective diels-alder cycloadditions
by: Wheeler, Steven E., et al.
Published: (2012)

High stereoselectivity on low temperature Diels-Alder reactions
by: Luiz Carlos da Silva Filho, et al.
Published: (2005-12-01)

STEREOSELECTIVE DIELS-ALDER REACTIONS OF A NEW CHIRAL CARBAMOYLNITROSO COMPOUND
by: Gouverneur, V, et al.
Published: (1990)

Computational Study of the Stereoselectivity of Diels-Alder Reactions of D-Glucose-Derived Dienophiles with Cyclopentadiene
by: S. C. Pellegrinet, et al.
Published: (2000-03-01)

Counterion-directed approach to the Diels-Alder paradigm: cascade synthesis of tricyclic fused cyclopropanes
by: Kiss, E, et al.
Published: (2016)

Diels-Alder reactivities of strained and unstrained cycloalkenes with normal and inverse-electron-demand dienes: activation barriers and distortion/interaction analysis.
by: Liu, F, et al.
Published: (2013)

Control of the exo and endo pathways of the Diels-Alder reaction by antibody catalysis.
by: Gouverneur, V, et al.
Published: (1993)

Mechanistic insights into stereoselective catalysis-the effects of counterions in a CuII-bissulfoximine-catalyzed Diels-Alder reaction.
by: Bolm, C, et al.
Published: (2007)

High-level Computational Study of the Site-, Facial- and Stereoselectivities for the Diels-Alder Reaction Between o-Benzoquinone and Norbornadiene
by: Ronald N. Warrener, et al.
Published: (2000-12-01)

Inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions of 4-silylated oxazoles
by: Pascal C. Ducept, et al.
Published: (2002-07-01)

DFT Investigation of the Stereoselectivity of the Lewis-Acid-Catalyzed Diels–Alder Reaction between 2,5-Dimethylfuran and Acrolein
by: Mohamed Chellegui, et al.
Published: (2025-01-01)

The Diels-Alder reaction: an update
by: Brocksom Timothy John, et al.
Published: (2001-01-01)

Diels-Alder exo selectivity in terminal-substituted dienes and dienophiles: experimental discoveries and computational explanations.
by: Lam, Y, et al.
Published: (2009)

Hyperconjugative Antiaromaticity Activates 4 H -Pyrazoles as Inverse-Electron-Demand Diels–Alder Dienes
by: Levandowski, Brian, et al.
Published: (2020)

Hetero Diels-Alder adduct formation between nitrosobenzene and tetra-methyl purpurogallin and its retro-Diels-Alder reaction
by: Gamenara Daniela, et al.
Published: (2001-01-01)

Asymmetric intramolecular Diels-Alder reactions
by: Essenfeld, Amy Pia
Published: (2005)

Tindak balas siklotambahan Diels-Alder /
by: 175536 Sim, Siaw Jiet
Published: (2001)

Diastereoselective Diels-Alder reactions. The role of the catalyst
by: Yifang Huang, et al.
Published: (2001-10-01)

Diels–Alder reactions in confined spaces: the influence of catalyst structure and the nature of active sites for the retro-Diels–Alder reaction
by: Ángel Cantín, et al.
Published: (2016-10-01)

Room Temperature Diels–Alder Reactions of 4-Vinylimidazoles
by: Brandon B. Fulton, et al.
Published: (2024-04-01)

An intramolecular diels-alder (IMDA) approach to biaryls.
by: Ong, Michelle Jui Hsien.
Published: (2010)

Diels-Alder Cycloaddition of Cyclopentadiene to a Bis-naphthoquinone
by: Letecia J. Duncalf, et al.
Published: (2000-02-01)

Diels–Alder Cycloaddition Reactions in Sustainable Media
by: Maria I. L. Soares, et al.
Published: (2022-02-01)

SUBSTITUTED 4-NITROSOPYRAZOLES IN THE DIELS-ALDER REACTION
by: Darya S. Volkova, et al.
Published: (2021-10-01)

CATALYSIS OF THE DIELS-ALDER REACTION BY ORGANOTIN HALIDES
by: Gabriele, Martin, et al.
Published: (1998-04-01)

Synthetic studies of the intramolecular Diels-Alder reaction
by: Warmus, Joseph Scott Warmus
Published: (2005)

Stereochemical aspects of the intramolecular Diels-Alder reaction
by: Gillis, Herbert Russell
Published: (2005)

A reação de Diels-Alder no início do século vinte um The Diels-Alder reaction at the beginning of the twenty-first century
by: Timothy John Brocksom, et al.
Published: (2010-01-01)

(Multi)functional polymers and composites via Diels-Alder reactions
by: J. Karger-Kocsis
Published: (2016-07-01)

Rapid chemical ligation of oligonucleotides by the Diels-Alder reaction.
by: El-Sagheer, A, et al.
Published: (2011)

Progress in Lewis-Acid-Templated Diels–Alder Reactions
by: Jun Ishihara
Published: (2024-03-01)

Radical cation Diels–Alder reactions of arylidene cycloalkanes
by: Kaii Nakayama, et al.
Published: (2022-08-01)

Aqueous Ti(IV)-Catalyzed Diels-Alder Reaction
by: Kyle E. Litz
Published: (2007-08-01)

A versatile Diels–Alder approach to functionalized hydroanthraquinones
by: Janina Beck, et al.
Published: (2020-11-01)

Diels-Alder reactions of organotin acetylides and the chemistry of the adducts
by: Evnin, Anthony Basil
Published: (2017)

The use of new ionic liquid in Diels-Alder reaction /
by: Mustaffa Shamsuddin, et al.
Published: (2003)