ENERGY-DISTRIBUTIONS IN THE CN(CHI-2-SIGMA+) FRAGMENT FROM THE INFRARED MULTIPLE-PHOTON DISSOCIATION OF CF3CN - A COMPARISON BETWEEN EXPERIMENTAL RESULTS AND THE PREDICTIONS OF STATISTICAL-THEORIES
Rotational and vibrational distributions in CN(X2Σ+) produced in the collisionless infrared multiple-photon dissociation (MPD) of CF3CN have been measured by laser-induced fluorescence. Both distributions appear Boltzmann, and may be assigned "temperatures" of Tvib = 2400 ± 200 K and Trot...
| Main Authors: | , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1983
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