The interaction between sodium alkyl sulfate surfactants and the oppositely charged polyelectrolyte, polyDMDAAC, at the air-water interface: the role of alkyl chain length and electrolyte and comparison with theoretical predictions.
The effect of alkyl chain length and electrolyte on the adsorption of sodium alkyl sulfate surfactants and the oppositely charged polyelectrolyte, polyDMDAAC, at the air-water interface has been investigated by surface tension and neutron reflectivity. The variations in the patterns of adsorption an...
| मुख्य लेखकों: | , , , , , , , |
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| स्वरूप: | Journal article |
| भाषा: | English |
| प्रकाशित: |
2007
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| _version_ | 1826274476738740224 |
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| author | Penfold, J Tucker, I Thomas, R Taylor, D Zhang, X Bell, C Breward, C Howell, P |
| author_facet | Penfold, J Tucker, I Thomas, R Taylor, D Zhang, X Bell, C Breward, C Howell, P |
| author_sort | Penfold, J |
| collection | OXFORD |
| description | The effect of alkyl chain length and electrolyte on the adsorption of sodium alkyl sulfate surfactants and the oppositely charged polyelectrolyte, polyDMDAAC, at the air-water interface has been investigated by surface tension and neutron reflectivity. The variations in the patterns of adsorption and surface tension behavior with alkyl chain length and electrolyte are discussed in the context of the competition between the formation of surface active surfactant/polyelectrolyte complexes and polyelectrolyte/surfactant micelle complexes in solution. A theoretical approach based on the law of mass action has been used to predict the surface effects arising from the competition between the formation of polyelectrolyte/surfactant surface and solution complexes and the formation of free surfactant micelles. This relatively straightforward model is shown to reproduce the principal features of the experimental results. |
| first_indexed | 2024-03-06T22:44:00Z |
| format | Journal article |
| id | oxford-uuid:5c8a51f9-0a11-438f-b648-adb5ff2b60f4 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T22:44:00Z |
| publishDate | 2007 |
| record_format | dspace |
| spelling | oxford-uuid:5c8a51f9-0a11-438f-b648-adb5ff2b60f42022-03-26T17:28:52ZThe interaction between sodium alkyl sulfate surfactants and the oppositely charged polyelectrolyte, polyDMDAAC, at the air-water interface: the role of alkyl chain length and electrolyte and comparison with theoretical predictions.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:5c8a51f9-0a11-438f-b648-adb5ff2b60f4EnglishSymplectic Elements at Oxford2007Penfold, JTucker, IThomas, RTaylor, DZhang, XBell, CBreward, CHowell, PThe effect of alkyl chain length and electrolyte on the adsorption of sodium alkyl sulfate surfactants and the oppositely charged polyelectrolyte, polyDMDAAC, at the air-water interface has been investigated by surface tension and neutron reflectivity. The variations in the patterns of adsorption and surface tension behavior with alkyl chain length and electrolyte are discussed in the context of the competition between the formation of surface active surfactant/polyelectrolyte complexes and polyelectrolyte/surfactant micelle complexes in solution. A theoretical approach based on the law of mass action has been used to predict the surface effects arising from the competition between the formation of polyelectrolyte/surfactant surface and solution complexes and the formation of free surfactant micelles. This relatively straightforward model is shown to reproduce the principal features of the experimental results. |
| spellingShingle | Penfold, J Tucker, I Thomas, R Taylor, D Zhang, X Bell, C Breward, C Howell, P The interaction between sodium alkyl sulfate surfactants and the oppositely charged polyelectrolyte, polyDMDAAC, at the air-water interface: the role of alkyl chain length and electrolyte and comparison with theoretical predictions. |
| title | The interaction between sodium alkyl sulfate surfactants and the oppositely charged polyelectrolyte, polyDMDAAC, at the air-water interface: the role of alkyl chain length and electrolyte and comparison with theoretical predictions. |
| title_full | The interaction between sodium alkyl sulfate surfactants and the oppositely charged polyelectrolyte, polyDMDAAC, at the air-water interface: the role of alkyl chain length and electrolyte and comparison with theoretical predictions. |
| title_fullStr | The interaction between sodium alkyl sulfate surfactants and the oppositely charged polyelectrolyte, polyDMDAAC, at the air-water interface: the role of alkyl chain length and electrolyte and comparison with theoretical predictions. |
| title_full_unstemmed | The interaction between sodium alkyl sulfate surfactants and the oppositely charged polyelectrolyte, polyDMDAAC, at the air-water interface: the role of alkyl chain length and electrolyte and comparison with theoretical predictions. |
| title_short | The interaction between sodium alkyl sulfate surfactants and the oppositely charged polyelectrolyte, polyDMDAAC, at the air-water interface: the role of alkyl chain length and electrolyte and comparison with theoretical predictions. |
| title_sort | interaction between sodium alkyl sulfate surfactants and the oppositely charged polyelectrolyte polydmdaac at the air water interface the role of alkyl chain length and electrolyte and comparison with theoretical predictions |
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