Reactions of Cyclopentadienyl-Amidinate Titanium Hydrazides with CO2, CS2, and Isocyanates: Ti=N-alpha Cycloaddition, Cycloaddition-Insertion, and Cycloaddition-NNR2 Group Transfer Reactions
We report a comprehensive combined experimental and DFT investigation of the synthesis, molecular and electronic structures, and reactivity of terminal hydrazido complexes with CO2, CS2, isocyanates, and isothiocyanates. Reaction of Cp*Ti{MeC(NiPr) 2}(NtBu) with hydrazines R1R 2NNH2 gave the structu...
| Main Authors: | , , , , , , , |
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| Format: | Journal article |
| Published: |
2011
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