First structural characterization of a delocalized, mixed-valent, triangular Cu37+ species: chemical and electrochemical oxidation of a CuII3(mu3-O) pyrazolate and electronic structure of the oxidation product.
The chemical or electrochemical one-electron oxidation of the all-CuII complex [Cu3(mu3-O)(mu-pz)3X3]2- leads to its formally CuII2CuIII analogue (pz = pyrazolato anion; X = Cl- and PhCOO-). The X-ray single-crystal structure and density functional theory analysis of the latter agree in revealing th...
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| Format: | Journal article |
| Language: | English |
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2005
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| _version_ | 1797070869002977280 |
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| author | Mezei, G McGrady, J Raptis, R |
| author_facet | Mezei, G McGrady, J Raptis, R |
| author_sort | Mezei, G |
| collection | OXFORD |
| description | The chemical or electrochemical one-electron oxidation of the all-CuII complex [Cu3(mu3-O)(mu-pz)3X3]2- leads to its formally CuII2CuIII analogue (pz = pyrazolato anion; X = Cl- and PhCOO-). The X-ray single-crystal structure and density functional theory analysis of the latter agree in revealing the delocalized nature of its mixed-valent Cu3(7+) core. |
| first_indexed | 2024-03-06T22:45:12Z |
| format | Journal article |
| id | oxford-uuid:5cee749b-e8ce-43f3-9adc-9c83377c013e |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T22:45:12Z |
| publishDate | 2005 |
| record_format | dspace |
| spelling | oxford-uuid:5cee749b-e8ce-43f3-9adc-9c83377c013e2022-03-26T17:31:17ZFirst structural characterization of a delocalized, mixed-valent, triangular Cu37+ species: chemical and electrochemical oxidation of a CuII3(mu3-O) pyrazolate and electronic structure of the oxidation product.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:5cee749b-e8ce-43f3-9adc-9c83377c013eEnglishSymplectic Elements at Oxford2005Mezei, GMcGrady, JRaptis, RThe chemical or electrochemical one-electron oxidation of the all-CuII complex [Cu3(mu3-O)(mu-pz)3X3]2- leads to its formally CuII2CuIII analogue (pz = pyrazolato anion; X = Cl- and PhCOO-). The X-ray single-crystal structure and density functional theory analysis of the latter agree in revealing the delocalized nature of its mixed-valent Cu3(7+) core. |
| spellingShingle | Mezei, G McGrady, J Raptis, R First structural characterization of a delocalized, mixed-valent, triangular Cu37+ species: chemical and electrochemical oxidation of a CuII3(mu3-O) pyrazolate and electronic structure of the oxidation product. |
| title | First structural characterization of a delocalized, mixed-valent, triangular Cu37+ species: chemical and electrochemical oxidation of a CuII3(mu3-O) pyrazolate and electronic structure of the oxidation product. |
| title_full | First structural characterization of a delocalized, mixed-valent, triangular Cu37+ species: chemical and electrochemical oxidation of a CuII3(mu3-O) pyrazolate and electronic structure of the oxidation product. |
| title_fullStr | First structural characterization of a delocalized, mixed-valent, triangular Cu37+ species: chemical and electrochemical oxidation of a CuII3(mu3-O) pyrazolate and electronic structure of the oxidation product. |
| title_full_unstemmed | First structural characterization of a delocalized, mixed-valent, triangular Cu37+ species: chemical and electrochemical oxidation of a CuII3(mu3-O) pyrazolate and electronic structure of the oxidation product. |
| title_short | First structural characterization of a delocalized, mixed-valent, triangular Cu37+ species: chemical and electrochemical oxidation of a CuII3(mu3-O) pyrazolate and electronic structure of the oxidation product. |
| title_sort | first structural characterization of a delocalized mixed valent triangular cu37 species chemical and electrochemical oxidation of a cuii3 mu3 o pyrazolate and electronic structure of the oxidation product |
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