Lanthanide-sensitized lanthanide luminescence: terbium-sensitized ytterbium luminescence in a trinuclear complex.

A heterotrinuclear lanthanide complex has been prepared which contains two terbium ions in DO3A-derived binding sites and a single ytterbium ion in a DTPA-like site. The luminescence properties of the system have been investigated, showing that the terbium remains in a seven-coordinate binding site...

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প্রধান লেখক: Faulkner, S, Pope, S
বিন্যাস: Journal article
ভাষা:English
প্রকাশিত: 2003
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author Faulkner, S
Pope, S
author_facet Faulkner, S
Pope, S
author_sort Faulkner, S
collection OXFORD
description A heterotrinuclear lanthanide complex has been prepared which contains two terbium ions in DO3A-derived binding sites and a single ytterbium ion in a DTPA-like site. The luminescence properties of the system have been investigated, showing that the terbium remains in a seven-coordinate binding site throughout the synthesis, while the ytterbium occupies the eight-coordinate site. Pumping the 488 nm absorption band of the terbium ion results in energy transfer to ytterbium with emission at 980 nm.
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spelling oxford-uuid:5d320b08-4dee-4c03-913e-81499b9d61d12022-03-26T17:32:53ZLanthanide-sensitized lanthanide luminescence: terbium-sensitized ytterbium luminescence in a trinuclear complex.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:5d320b08-4dee-4c03-913e-81499b9d61d1EnglishSymplectic Elements at Oxford2003Faulkner, SPope, SA heterotrinuclear lanthanide complex has been prepared which contains two terbium ions in DO3A-derived binding sites and a single ytterbium ion in a DTPA-like site. The luminescence properties of the system have been investigated, showing that the terbium remains in a seven-coordinate binding site throughout the synthesis, while the ytterbium occupies the eight-coordinate site. Pumping the 488 nm absorption band of the terbium ion results in energy transfer to ytterbium with emission at 980 nm.
spellingShingle Faulkner, S
Pope, S
Lanthanide-sensitized lanthanide luminescence: terbium-sensitized ytterbium luminescence in a trinuclear complex.
title Lanthanide-sensitized lanthanide luminescence: terbium-sensitized ytterbium luminescence in a trinuclear complex.
title_full Lanthanide-sensitized lanthanide luminescence: terbium-sensitized ytterbium luminescence in a trinuclear complex.
title_fullStr Lanthanide-sensitized lanthanide luminescence: terbium-sensitized ytterbium luminescence in a trinuclear complex.
title_full_unstemmed Lanthanide-sensitized lanthanide luminescence: terbium-sensitized ytterbium luminescence in a trinuclear complex.
title_short Lanthanide-sensitized lanthanide luminescence: terbium-sensitized ytterbium luminescence in a trinuclear complex.
title_sort lanthanide sensitized lanthanide luminescence terbium sensitized ytterbium luminescence in a trinuclear complex
work_keys_str_mv AT faulkners lanthanidesensitizedlanthanideluminescenceterbiumsensitizedytterbiumluminescenceinatrinuclearcomplex
AT popes lanthanidesensitizedlanthanideluminescenceterbiumsensitizedytterbiumluminescenceinatrinuclearcomplex