Lanthanide-sensitized lanthanide luminescence: terbium-sensitized ytterbium luminescence in a trinuclear complex.
A heterotrinuclear lanthanide complex has been prepared which contains two terbium ions in DO3A-derived binding sites and a single ytterbium ion in a DTPA-like site. The luminescence properties of the system have been investigated, showing that the terbium remains in a seven-coordinate binding site...
প্রধান লেখক: | , |
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বিন্যাস: | Journal article |
ভাষা: | English |
প্রকাশিত: |
2003
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_version_ | 1826274605782794240 |
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author | Faulkner, S Pope, S |
author_facet | Faulkner, S Pope, S |
author_sort | Faulkner, S |
collection | OXFORD |
description | A heterotrinuclear lanthanide complex has been prepared which contains two terbium ions in DO3A-derived binding sites and a single ytterbium ion in a DTPA-like site. The luminescence properties of the system have been investigated, showing that the terbium remains in a seven-coordinate binding site throughout the synthesis, while the ytterbium occupies the eight-coordinate site. Pumping the 488 nm absorption band of the terbium ion results in energy transfer to ytterbium with emission at 980 nm. |
first_indexed | 2024-03-06T22:45:59Z |
format | Journal article |
id | oxford-uuid:5d320b08-4dee-4c03-913e-81499b9d61d1 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-06T22:45:59Z |
publishDate | 2003 |
record_format | dspace |
spelling | oxford-uuid:5d320b08-4dee-4c03-913e-81499b9d61d12022-03-26T17:32:53ZLanthanide-sensitized lanthanide luminescence: terbium-sensitized ytterbium luminescence in a trinuclear complex.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:5d320b08-4dee-4c03-913e-81499b9d61d1EnglishSymplectic Elements at Oxford2003Faulkner, SPope, SA heterotrinuclear lanthanide complex has been prepared which contains two terbium ions in DO3A-derived binding sites and a single ytterbium ion in a DTPA-like site. The luminescence properties of the system have been investigated, showing that the terbium remains in a seven-coordinate binding site throughout the synthesis, while the ytterbium occupies the eight-coordinate site. Pumping the 488 nm absorption band of the terbium ion results in energy transfer to ytterbium with emission at 980 nm. |
spellingShingle | Faulkner, S Pope, S Lanthanide-sensitized lanthanide luminescence: terbium-sensitized ytterbium luminescence in a trinuclear complex. |
title | Lanthanide-sensitized lanthanide luminescence: terbium-sensitized ytterbium luminescence in a trinuclear complex. |
title_full | Lanthanide-sensitized lanthanide luminescence: terbium-sensitized ytterbium luminescence in a trinuclear complex. |
title_fullStr | Lanthanide-sensitized lanthanide luminescence: terbium-sensitized ytterbium luminescence in a trinuclear complex. |
title_full_unstemmed | Lanthanide-sensitized lanthanide luminescence: terbium-sensitized ytterbium luminescence in a trinuclear complex. |
title_short | Lanthanide-sensitized lanthanide luminescence: terbium-sensitized ytterbium luminescence in a trinuclear complex. |
title_sort | lanthanide sensitized lanthanide luminescence terbium sensitized ytterbium luminescence in a trinuclear complex |
work_keys_str_mv | AT faulkners lanthanidesensitizedlanthanideluminescenceterbiumsensitizedytterbiumluminescenceinatrinuclearcomplex AT popes lanthanidesensitizedlanthanideluminescenceterbiumsensitizedytterbiumluminescenceinatrinuclearcomplex |