Formation of a σ-alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4]
Addition of H2 to the precursor [Rh(Cyp2P(CH2)2PCyp2)(η2 :η2 -C7H8)][BArF 4] gives the σ-alkane complex [Rh(Cyp2P(CH2)2PCyp2)(η2 :η2 -C7H12)][BArF 4] by a single-crystal to single–crystal reaction, as characterized by X-ray crystallography, SSNMR spectroscopy and periodic DFT. An unexpected rearrang...
সম্পূর্ণ বিবরণ
গ্রন্থ-পঞ্জীর বিবরন
| প্রধান লেখক: |
McKay, A,
Krämer, T,
Rees, N,
Thompson, A,
Christensen, K,
Macgregor, S,
Weller, A |
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| বিন্যাস: | Journal article
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| প্রকাশিত: |
American Chemical Society
2016
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