Formation of a σ-alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4]

Formation of a σ-alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4]

Addition of H2 to the precursor [Rh(Cyp2P(CH2)2PCyp2)(η2 :η2 -C7H8)][BArF 4] gives the σ-alkane complex [Rh(Cyp2P(CH2)2PCyp2)(η2 :η2 -C7H12)][BArF 4] by a single-crystal to single–crystal reaction, as characterized by X-ray crystallography, SSNMR spectroscopy and periodic DFT. An unexpected rearrang...

Πλήρης περιγραφή

Λεπτομέρειες βιβλιογραφικής εγγραφής
Κύριοι συγγραφείς:	McKay, A, Krämer, T, Rees, N, Thompson, A, Christensen, K, Macgregor, S, Weller, A
Μορφή:	Journal article
Έκδοση:	American Chemical Society 2016

Παρόμοια τεκμήρια

Modulation of σ-alkane interactions in [Rh(L2)(alkane)]+ Solid-State Molecular Organometallic (SMOM) systems by variation of the chelating phosphine and alkane: Access to η2,η2-σ-alkane Rh(I), η1-σ-alkane Rh(III) complexes, and alkane encapsulation
ανά: Martinez-Martinez, AJ, κ.ά.
Έκδοση: (2018)

Solid-state synthesis and characterization of σ-alkane complexes, [Rh(L2)(η(2),η(2)-C7H12)][BAr(F)4] (L2 = bidentate chelating phosphine)
ανά: Pike, S, κ.ά.
Έκδοση: (2014)

A d10 Ag(I) amine–borane σ-complex and comparison with a d8 Rh(I) analogue: structures on the η1 to η2:η2 continuum
ανά: Johnson, A, κ.ά.
Έκδοση: (2019)

Dehydrocoupling of phosphine-boranes using the [RhCp∗Me(PMe3)(CH2Cl2)][BArF 4] precatalyst: Stoichiometric and catalytic studies
ανά: Hooper, T, κ.ά.
Έκδοση: (2015)

Spin-locality of η 2 and η ¯ 2 $$ {\overline{\eta}}^2 $$ quartic higher-spin vertices
ανά: V. E. Didenko, κ.ά.
Έκδοση: (2020-12-01)

Synthesis and reactivity of nickel-stabilised µ2:η2,η2-P2, As2 and PAs units
ανά: Hierlmeier, G, κ.ά.
Έκδοση: (2017)

Photon beam asymmetry Σ for η and η′ photoproduction from the proton
ανά: P. Collins, κ.ά.
Έκδοση: (2017-08-01)

μ-Carbonyl-bis(carbonyl{η5-[tricarbonyl(η6-2-methylindenyl)chromium(0)]rhodium(III)})(Rh—Rh)
ανά: Christophe Werlé, κ.ά.
Έκδοση: (2019-05-01)

Room temperature acceptorless alkane dehydrogenation from molecular σ-alkane complexes
ανά: McKay, AI, κ.ά.
Έκδοση: (2019)

The role of neutral Rh(PONOP)H, free NMe2H, boronium and ammonium salts in the dehydrocoupling of dimethylamine-borane using the cationic pincer [Rh(PONOP)(η2-H2)]+ catalyst†‡
ανά: Spearing-Ewyn, E, κ.ά.
Έκδοση: (2019)

Crystal structure of (η2,η2-cycloocta-1,5-diene)(η5-indenyl)cobalt(I)
ανά: Phillip Jungk, κ.ά.
Έκδοση: (2016-01-01)

Synthesis of "phosphine tethered" η2-allene and μ-η1:η2-alkenyl complexes: Facile P-Cα bond formation and C-H activation reactions of bis(diphenylphosphino)methane with [Fe2(CO)6(μ-ER){μ-η1:η
ανά: Doherty, S, κ.ά.
Έκδοση: (1996)

Synthese und Reaktivität von Nickel-stabilisierten μ2:η2,η2-P2-,As2-und PAs-Einheiten
ανά: Hierlmeier, G, κ.ά.
Έκδοση: (2017)

Crystal structure of bis[(η5-cyclopentadienyl)(η1 :η2-2-trimethylsilylethinyl)( chloro)titanium(III)], [CpTiCl(CCSiMe3)]2
ανά: Spannenberg A., κ.ά.
Έκδοση: (2001-04-01)

Reversible addition of water to the high-hydride-content cluster [Rh6(PiPr3)6H12][BArF4]2. Synthesis and Structure of [Rh6PiPr3)6H11(OH)][BArF4]2.
ανά: Douglas, T, κ.ά.
Έκδοση: (2008)

C-H bond activation of benzene by unsaturated η2-cyclopropene and η2-benzyne complexes of niobium.
ανά: Boulho, C, κ.ά.
Έκδοση: (2010)

Crystal structure of bis(η2-ethylene)(η5-pentamethylcyclopentadienyl)cobalt
ανά: Chandika D. Ramful, κ.ά.
Έκδοση: (2016-09-01)

Study of B-meson decays to ηcK(*), ηc(2S)K(*), and ηcγK(*)
ανά: Aubert, B, κ.ά.
Έκδοση: (2008)

Crystal structures of the (η2:η2-cycloocta-1,5-diene)(η6-toluene)iridium(I) cation and μ-chlorido-iridium(III) complexes of 2-(phosphinito)- and 2-(phosphinomethyl)anthraquinone ligands
ανά: Sachin Thackeray, κ.ά.
Έκδοση: (2024-10-01)

Exploring (Ph2PCH2CH2)2E Ligand Space (E = O, S, PPh) in RhI Alkene Complexes as Potential Hydroacylation Catalysts
ανά: Pike, S, κ.ά.
Έκδοση: (2011)

Correction: Dehydrocoupling of phosphine-boranes using the [RhCp∗Me(PMe3)(CH2Cl2)][BArF 4] precatalyst: stoichiometric and catalytic studies (Chem. Sci. (2016) DOI: 10.1039/c5sc04150c)
ανά: Hooper, T, κ.ά.
Έκδοση: (2016)

SYNTHESIS, CHARACTERIZATION AND THERMAL BEHAVIOUR OF CALCIUM AND STRONTIUM 2, 2, 6, 6-TETRAMETHYL-3,5-HEPTANEDIONATE COMPLEXES. CRYSTAL STRUCTURE OF [Sr(μ, η2-thd)(η2-thd)(η2-MeOC2H4OH)]2
ανά: Guillon, Hervé, κ.ά.
Έκδοση: (1997-10-01)

(η2,η2-Cycloocta-1,5-diene)[2-(diphenylphosphanylmethyl)pyridine-κ2N,P]rhodium(I) tetrafluoridoborate 1,2-dichloroethane monosolvate
ανά: Siping Wei, κ.ά.
Έκδοση: (2016-08-01)

Beam asymmetry Σ for the photoproduction of η and η ′ mesons at E γ = 8.8 GeV
ανά: Fanelli, Cristiano, κ.ά.
Έκδοση: (2022)

Beam asymmetry Σ for the photoproduction of η and η ′ mesons at E γ = 8.8 GeV
Έκδοση: (2021)

Crystal structure of [2,2-bis(η5-pentamethylcyclopentadienyl)-bis-(μ,η1:η2- 2-trimethylsilyl-ethinyl)titanium(IV) lithium] [2,2-bis(η5-pentamethy Icy clopentadienyl)- oxotitanium(III)–tetrahydrofurane (1/0.5), C50H78LiOSi2Ti2 · 0.5C4H8O
ανά: Spannenberg A., κ.ά.
Έκδοση: (2001-04-01)

(η4-Bicyclo[2.2.1]hepta-2,5-diene)bis(η2-3,5-di-tert-butyl-1,2,4-diazaphospholido)ruthenium
ανά: Lili Ren, κ.ά.
Έκδοση: (2016-01-01)

Crystal structure of (η5-pentamethylcyclopentadienyl)(η5-1-(2,2-dimethylpropyl) cyclopentadienyl)titaniumdichloride, C20H30Cl2Ti
ανά: Stroot J., κ.ά.
Έκδοση: (2002-12-01)

Crystal structure of (η5-pentamethylcyclopentadienyl)(η5-1-(2,2-dimethylpropyl) cyclopentadienyl)titaniumdichloride, C20H30Cl2Ti
ανά: Stroot J., κ.ά.
Έκδοση: (2002-12-01)

Measurement of η′ → ηπ+π− with KLOE and KLOE-2
ανά: Redmer C.F.
Έκδοση: (2012-12-01)

[Ir(PPh3)2(H)2(ClCH2CH2Cl)][BArF4]: a well characterised transition metal dichloroethane complex.
ανά: Moxham, G, κ.ά.
Έκδοση: (2007)

J/ψ and ψ(2S) radiative transitions to ηc
ανά: Mitchell, R, κ.ά.
Έκδοση: (2009)

(2,2′-Bipyridyl)(η6-p-cymene)iodidoruthenium(II) hexafluoridophosphate
ανά: Monsuru T. Kelani, κ.ά.
Έκδοση: (2023-05-01)

Challenges in cyclometalation : steric effects leading to competing pathways and η1,η2-cyclometalated iridium(iii) complexes
ανά: Chen, Jeremy Houguang, κ.ά.
Έκδοση: (2020)

Pseudoscalar transition form factors: (g − 2) of the muon, pseudoscalar decays into lepton pairs, and the η – η′ mixing
ανά: Masjuan Pere, κ.ά.
Έκδοση: (2016-01-01)

An unprecedented regiospecific attack of phosphorus nucleophiles at Cα of the allenyl ligand in [Fe2(CO)6(μ-PPh2){μ-η 1:η2 α,β-(H)C α=Cβ=CγH2}]
ανά: Doherty, S, κ.ά.
Έκδοση: (1996)

Bis(μ[subscript 2]-η[superscript 2]:η[superscript 2]-2,4,6-trimethylbenzonitrile)bis[(N-isopropyl-3,5-dimethylanilido)molybdenum(III)](Mo-Mo)
ανά: Moroz, Yurii S., κ.ά.
Έκδοση: (2012)

Chelating monoborane phosphines: Rational and high-yield synthesis of [(COD)Rh{(eta(2)-BH(3))Ph(2)PCH(2)PPh(2)}][PF(6)] (COD=1,5-cyclooctadiene)
ανά: Ingleson, M, κ.ά.
Έκδοση: (2001)

Crystal structure of chlorobis(η5 -pentamethylcyclopentadienyl)- (η3-2-methyl-2-propenyl)zirconium, Zr(C4H7)(C10H15)2Cl
ανά: Ernst R. D., κ.ά.
Έκδοση: (2004-04-01)

Dichlorido[(1,2,3,3a,8b-η)-2,4-dimethylcyclopenta[b]indolyl)(η5-pentamethylcyclopentadienyl)zirconium(IV)
ανά: Michael G. Medvedev, κ.ά.
Έκδοση: (2016-09-01)