Synthesis and evaluation of 4,4 ',6,6 '-tetrasubstituted binaphtholphosphate dirhodium(II) complexes as catalysts in enantioselective carbonyl ylide formation-cycloaddition reactions
The synthesis of tetrakis[4,4′,6,6′-tetrasubstituted-1, 1′-bi-2-naphtholphosphate]dirhodium(II) complexes, and their use as catalysts in the enantioselective tandem carbonyl ylide formation- intramolecular 1,3-dipolar cycloaddition of an unsaturated 2-diazo-3,6- diketoester, generating cycloadduct i...
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| Format: | Journal article |
| Language: | English |
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2003
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| _version_ | 1797071012083269632 |
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| author | Hodgson, D Selden, D Dossetter, A |
| author_facet | Hodgson, D Selden, D Dossetter, A |
| author_sort | Hodgson, D |
| collection | OXFORD |
| description | The synthesis of tetrakis[4,4′,6,6′-tetrasubstituted-1, 1′-bi-2-naphtholphosphate]dirhodium(II) complexes, and their use as catalysts in the enantioselective tandem carbonyl ylide formation- intramolecular 1,3-dipolar cycloaddition of an unsaturated 2-diazo-3,6- diketoester, generating cycloadduct in up to 86% ee, is described. © 2003 Elsevier Ltd. All rights reserved. |
| first_indexed | 2024-03-06T22:47:08Z |
| format | Journal article |
| id | oxford-uuid:5d8d0db9-28e7-4f6d-9aef-5cc53c0d6a46 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T22:47:08Z |
| publishDate | 2003 |
| record_format | dspace |
| spelling | oxford-uuid:5d8d0db9-28e7-4f6d-9aef-5cc53c0d6a462022-03-26T17:35:10ZSynthesis and evaluation of 4,4 ',6,6 '-tetrasubstituted binaphtholphosphate dirhodium(II) complexes as catalysts in enantioselective carbonyl ylide formation-cycloaddition reactionsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:5d8d0db9-28e7-4f6d-9aef-5cc53c0d6a46EnglishSymplectic Elements at Oxford2003Hodgson, DSelden, DDossetter, AThe synthesis of tetrakis[4,4′,6,6′-tetrasubstituted-1, 1′-bi-2-naphtholphosphate]dirhodium(II) complexes, and their use as catalysts in the enantioselective tandem carbonyl ylide formation- intramolecular 1,3-dipolar cycloaddition of an unsaturated 2-diazo-3,6- diketoester, generating cycloadduct in up to 86% ee, is described. © 2003 Elsevier Ltd. All rights reserved. |
| spellingShingle | Hodgson, D Selden, D Dossetter, A Synthesis and evaluation of 4,4 ',6,6 '-tetrasubstituted binaphtholphosphate dirhodium(II) complexes as catalysts in enantioselective carbonyl ylide formation-cycloaddition reactions |
| title | Synthesis and evaluation of 4,4 ',6,6 '-tetrasubstituted binaphtholphosphate dirhodium(II) complexes as catalysts in enantioselective carbonyl ylide formation-cycloaddition reactions |
| title_full | Synthesis and evaluation of 4,4 ',6,6 '-tetrasubstituted binaphtholphosphate dirhodium(II) complexes as catalysts in enantioselective carbonyl ylide formation-cycloaddition reactions |
| title_fullStr | Synthesis and evaluation of 4,4 ',6,6 '-tetrasubstituted binaphtholphosphate dirhodium(II) complexes as catalysts in enantioselective carbonyl ylide formation-cycloaddition reactions |
| title_full_unstemmed | Synthesis and evaluation of 4,4 ',6,6 '-tetrasubstituted binaphtholphosphate dirhodium(II) complexes as catalysts in enantioselective carbonyl ylide formation-cycloaddition reactions |
| title_short | Synthesis and evaluation of 4,4 ',6,6 '-tetrasubstituted binaphtholphosphate dirhodium(II) complexes as catalysts in enantioselective carbonyl ylide formation-cycloaddition reactions |
| title_sort | synthesis and evaluation of 4 4 6 6 tetrasubstituted binaphtholphosphate dirhodium ii complexes as catalysts in enantioselective carbonyl ylide formation cycloaddition reactions |
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