Dihalogeno(diphosphane)metal(II) complexes (metal = Co, Ni, Pd) as pre-catalysts for the vinyl/addition polymerization of norbornene - elucidation of the activation process with B(C6F5)(3)/AlEt3 or Ag[closo-1-CB11H12] and evidence for the in situ formation of "naked" Pd2+ as a highly active species
Dihalogenometal(II) complexes with bidentate phosphane ligands of the general type [M{Ph2P(CH2)nPPh2} X2] with n = 2 to 5, X = Cl or Br and M = Co, Ni or Pd have been utilized as catalysts for the vinyl/addition polymerization of norbornene. These complexes can be activated with the Lewis-acids meth...
| Main Authors: | , , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
2003
|