A new model for Sb deposition in the French Massif Central based upon thermodynamic modeling of the mineralizing fluid

A new model for antimony (Sb) deposits in the Haut-Allier area of the French Massif Central is proposed, based on thermodynamic modeling of the mineralizing fluid. The Sb deposits in the research area contain stibnite and berthierite as Sb minerals, and occur in veins crosscutting gneiss lenses. The...

Full description

Bibliographic Details
Main Authors: Van Hinsberg, V, Zinngrebe, E, de Wijs, C, Vriend, S
Format: Conference item
Published: 2003
_version_ 1797071452278620160
author Van Hinsberg, V
Zinngrebe, E
de Wijs, C
Vriend, S
author_facet Van Hinsberg, V
Zinngrebe, E
de Wijs, C
Vriend, S
author_sort Van Hinsberg, V
collection OXFORD
description A new model for antimony (Sb) deposits in the Haut-Allier area of the French Massif Central is proposed, based on thermodynamic modeling of the mineralizing fluid. The Sb deposits in the research area contain stibnite and berthierite as Sb minerals, and occur in veins crosscutting gneiss lenses. The surrounding schist host rock is non-mineralized. Thermodynamic modeling of the ore-fluid shows that no Sb minerals will precipitate if the fluid is buffered by alteration reactions in the host rock. However, brittle fractures, developed in the gneiss lenses during uplift, channelize the fluid flow, which eventually results in the loss of contact with the buffering environment. With lowering temperatures the Sb solubility sharply decreases in this unbuffered fluid and Sb-minerals precipitate. The schists continue to allow pervasive fluid flow instead, buffering the fluid outside the stibnite stability field and no Sb deposits are therefore present. © 2003 Elsevier Science B.V. All rights reserved.
first_indexed 2024-03-06T22:53:27Z
format Conference item
id oxford-uuid:5f93fac8-ce1c-4f92-a3b5-8f24b152c352
institution University of Oxford
last_indexed 2024-03-06T22:53:27Z
publishDate 2003
record_format dspace
spelling oxford-uuid:5f93fac8-ce1c-4f92-a3b5-8f24b152c3522022-03-26T17:47:49ZA new model for Sb deposition in the French Massif Central based upon thermodynamic modeling of the mineralizing fluidConference itemhttp://purl.org/coar/resource_type/c_5794uuid:5f93fac8-ce1c-4f92-a3b5-8f24b152c352Symplectic Elements at Oxford2003Van Hinsberg, VZinngrebe, Ede Wijs, CVriend, SA new model for antimony (Sb) deposits in the Haut-Allier area of the French Massif Central is proposed, based on thermodynamic modeling of the mineralizing fluid. The Sb deposits in the research area contain stibnite and berthierite as Sb minerals, and occur in veins crosscutting gneiss lenses. The surrounding schist host rock is non-mineralized. Thermodynamic modeling of the ore-fluid shows that no Sb minerals will precipitate if the fluid is buffered by alteration reactions in the host rock. However, brittle fractures, developed in the gneiss lenses during uplift, channelize the fluid flow, which eventually results in the loss of contact with the buffering environment. With lowering temperatures the Sb solubility sharply decreases in this unbuffered fluid and Sb-minerals precipitate. The schists continue to allow pervasive fluid flow instead, buffering the fluid outside the stibnite stability field and no Sb deposits are therefore present. © 2003 Elsevier Science B.V. All rights reserved.
spellingShingle Van Hinsberg, V
Zinngrebe, E
de Wijs, C
Vriend, S
A new model for Sb deposition in the French Massif Central based upon thermodynamic modeling of the mineralizing fluid
title A new model for Sb deposition in the French Massif Central based upon thermodynamic modeling of the mineralizing fluid
title_full A new model for Sb deposition in the French Massif Central based upon thermodynamic modeling of the mineralizing fluid
title_fullStr A new model for Sb deposition in the French Massif Central based upon thermodynamic modeling of the mineralizing fluid
title_full_unstemmed A new model for Sb deposition in the French Massif Central based upon thermodynamic modeling of the mineralizing fluid
title_short A new model for Sb deposition in the French Massif Central based upon thermodynamic modeling of the mineralizing fluid
title_sort new model for sb deposition in the french massif central based upon thermodynamic modeling of the mineralizing fluid
work_keys_str_mv AT vanhinsbergv anewmodelforsbdepositioninthefrenchmassifcentralbaseduponthermodynamicmodelingofthemineralizingfluid
AT zinngrebee anewmodelforsbdepositioninthefrenchmassifcentralbaseduponthermodynamicmodelingofthemineralizingfluid
AT dewijsc anewmodelforsbdepositioninthefrenchmassifcentralbaseduponthermodynamicmodelingofthemineralizingfluid
AT vriends anewmodelforsbdepositioninthefrenchmassifcentralbaseduponthermodynamicmodelingofthemineralizingfluid
AT vanhinsbergv newmodelforsbdepositioninthefrenchmassifcentralbaseduponthermodynamicmodelingofthemineralizingfluid
AT zinngrebee newmodelforsbdepositioninthefrenchmassifcentralbaseduponthermodynamicmodelingofthemineralizingfluid
AT dewijsc newmodelforsbdepositioninthefrenchmassifcentralbaseduponthermodynamicmodelingofthemineralizingfluid
AT vriends newmodelforsbdepositioninthefrenchmassifcentralbaseduponthermodynamicmodelingofthemineralizingfluid