Perovskite photovoltachromic cells for building integration

Photovoltachromic devices combine photovoltaic and electrochromic behaviours to enable adjustable transparency glazing, where the photovoltaic component supplies the power to drive the coloration. Such stand-alone, self-powered devices are of commercial interest for integration into windows and surf...

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Asıl Yazarlar: Cannavale, A, Eperon, G, Cossari, P, Abate, A, Snaith, H, Gigli, G
Materyal Türü: Journal article
Baskı/Yayın Bilgisi: Royal Society of Chemistry 2015
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author Cannavale, A
Eperon, G
Cossari, P
Abate, A
Snaith, H
Gigli, G
author_facet Cannavale, A
Eperon, G
Cossari, P
Abate, A
Snaith, H
Gigli, G
author_sort Cannavale, A
collection OXFORD
description Photovoltachromic devices combine photovoltaic and electrochromic behaviours to enable adjustable transparency glazing, where the photovoltaic component supplies the power to drive the coloration. Such stand-alone, self-powered devices are of commercial interest for integration into windows and surfaces of buildings and vehicles. Here, we report for the first time a perovskite-based photovoltachromic device with self-adaptive transparency. This multifunctional device is capable of producing electrical power by solar energy conversion as well as undergoing a chromic transition from neutral-color semi-transparent to dark blue-tinted when irradiated with solar light, without any additional external bias. The combination of semi-transparent perovskite photovoltaic and solid-state electrochromic cells enables fully solid-state photovoltachromic devices with 26% (or 16%) average visible transmittance and 3.7% (or 5.5%) maximum light power conversion efficiency. Upon activating the self-tinting, the average visible transmittance drops to 8.4% (or 5.5%). These results represent a significant step towards the commercialization of photovoltachromic building envelopes.
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spelling oxford-uuid:5fc1201b-8d23-442c-9cd3-0847467247f02022-03-26T17:48:55ZPerovskite photovoltachromic cells for building integrationJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:5fc1201b-8d23-442c-9cd3-0847467247f0Symplectic Elements at OxfordRoyal Society of Chemistry2015Cannavale, AEperon, GCossari, PAbate, ASnaith, HGigli, GPhotovoltachromic devices combine photovoltaic and electrochromic behaviours to enable adjustable transparency glazing, where the photovoltaic component supplies the power to drive the coloration. Such stand-alone, self-powered devices are of commercial interest for integration into windows and surfaces of buildings and vehicles. Here, we report for the first time a perovskite-based photovoltachromic device with self-adaptive transparency. This multifunctional device is capable of producing electrical power by solar energy conversion as well as undergoing a chromic transition from neutral-color semi-transparent to dark blue-tinted when irradiated with solar light, without any additional external bias. The combination of semi-transparent perovskite photovoltaic and solid-state electrochromic cells enables fully solid-state photovoltachromic devices with 26% (or 16%) average visible transmittance and 3.7% (or 5.5%) maximum light power conversion efficiency. Upon activating the self-tinting, the average visible transmittance drops to 8.4% (or 5.5%). These results represent a significant step towards the commercialization of photovoltachromic building envelopes.
spellingShingle Cannavale, A
Eperon, G
Cossari, P
Abate, A
Snaith, H
Gigli, G
Perovskite photovoltachromic cells for building integration
title Perovskite photovoltachromic cells for building integration
title_full Perovskite photovoltachromic cells for building integration
title_fullStr Perovskite photovoltachromic cells for building integration
title_full_unstemmed Perovskite photovoltachromic cells for building integration
title_short Perovskite photovoltachromic cells for building integration
title_sort perovskite photovoltachromic cells for building integration
work_keys_str_mv AT cannavalea perovskitephotovoltachromiccellsforbuildingintegration
AT eperong perovskitephotovoltachromiccellsforbuildingintegration
AT cossarip perovskitephotovoltachromiccellsforbuildingintegration
AT abatea perovskitephotovoltachromiccellsforbuildingintegration
AT snaithh perovskitephotovoltachromiccellsforbuildingintegration
AT giglig perovskitephotovoltachromiccellsforbuildingintegration