FE3O4 ACTIVITIES IN FE-TI SPINEL SOLID-SOLUTIONS
The activity of Fe3O4 in Fe3O4-Fe2TiO4 solid solutions has been experimentally determined at 800°C and 900°C at 1 atm pressure. The activity-composition relations deviate markedly from "ideal' (a = X2) behavior, requiring consideration of Fe 2+-Fe3+ order on the ulvospinel-magnetite join....
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| Format: | Journal article |
| Language: | English |
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1994
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| _version_ | 1797071506402967552 |
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| author | Woodland, A Wood, B |
| author_facet | Woodland, A Wood, B |
| author_sort | Woodland, A |
| collection | OXFORD |
| description | The activity of Fe3O4 in Fe3O4-Fe2TiO4 solid solutions has been experimentally determined at 800°C and 900°C at 1 atm pressure. The activity-composition relations deviate markedly from "ideal' (a = X2) behavior, requiring consideration of Fe 2+-Fe3+ order on the ulvospinel-magnetite join. We have developed a solution model that takes explicit account of order-disorder and the measured activity-composition relations. The derived interaction parameters fit our activity-composition data together with other activity and cation distribution data available in the literature over the temperature range of 800-1300°C. -Authors |
| first_indexed | 2024-03-06T22:54:16Z |
| format | Journal article |
| id | oxford-uuid:5fd516a3-ba84-4dfa-8728-f9a6064d9036 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T22:54:16Z |
| publishDate | 1994 |
| record_format | dspace |
| spelling | oxford-uuid:5fd516a3-ba84-4dfa-8728-f9a6064d90362022-03-26T17:49:32ZFE3O4 ACTIVITIES IN FE-TI SPINEL SOLID-SOLUTIONSJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:5fd516a3-ba84-4dfa-8728-f9a6064d9036EnglishSymplectic Elements at Oxford1994Woodland, AWood, BThe activity of Fe3O4 in Fe3O4-Fe2TiO4 solid solutions has been experimentally determined at 800°C and 900°C at 1 atm pressure. The activity-composition relations deviate markedly from "ideal' (a = X2) behavior, requiring consideration of Fe 2+-Fe3+ order on the ulvospinel-magnetite join. We have developed a solution model that takes explicit account of order-disorder and the measured activity-composition relations. The derived interaction parameters fit our activity-composition data together with other activity and cation distribution data available in the literature over the temperature range of 800-1300°C. -Authors |
| spellingShingle | Woodland, A Wood, B FE3O4 ACTIVITIES IN FE-TI SPINEL SOLID-SOLUTIONS |
| title | FE3O4 ACTIVITIES IN FE-TI SPINEL SOLID-SOLUTIONS |
| title_full | FE3O4 ACTIVITIES IN FE-TI SPINEL SOLID-SOLUTIONS |
| title_fullStr | FE3O4 ACTIVITIES IN FE-TI SPINEL SOLID-SOLUTIONS |
| title_full_unstemmed | FE3O4 ACTIVITIES IN FE-TI SPINEL SOLID-SOLUTIONS |
| title_short | FE3O4 ACTIVITIES IN FE-TI SPINEL SOLID-SOLUTIONS |
| title_sort | fe3o4 activities in fe ti spinel solid solutions |
| work_keys_str_mv | AT woodlanda fe3o4activitiesinfetispinelsolidsolutions AT woodb fe3o4activitiesinfetispinelsolidsolutions |