The 248 nm photolysis of NO2/N2O4: Time-resolved Fourier transform infrared emission from NO and NO2, and quenching of NO (v=5-8)

The 248 nm photolysis of NO2 results in an inverted vibrational distribution in NO(v) which agrees well with previous REMPI measurements. It was shown that the quenching of the higher levels in collisions with NO2 have clear importance of resonance energy transfer to the NO2(0,0,1) level. Emission f...

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Main Authors: Morrell, C, Breheny, C, Haverd, V, Cawley, A, Hancock, G
Format: Journal article
Language:English
Published: 2002
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author Morrell, C
Breheny, C
Haverd, V
Cawley, A
Hancock, G
author_facet Morrell, C
Breheny, C
Haverd, V
Cawley, A
Hancock, G
author_sort Morrell, C
collection OXFORD
description The 248 nm photolysis of NO2 results in an inverted vibrational distribution in NO(v) which agrees well with previous REMPI measurements. It was shown that the quenching of the higher levels in collisions with NO2 have clear importance of resonance energy transfer to the NO2(0,0,1) level. Emission from NO2 was found, produced from the photolysis of N2O4, and its spectral signature was similar to that resulting from electronic excitation of NO2.
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spelling oxford-uuid:5ff3ad70-7993-47e2-a617-d4e2ef09251a2022-03-26T17:50:14ZThe 248 nm photolysis of NO2/N2O4: Time-resolved Fourier transform infrared emission from NO and NO2, and quenching of NO (v=5-8)Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:5ff3ad70-7993-47e2-a617-d4e2ef09251aEnglishSymplectic Elements at Oxford2002Morrell, CBreheny, CHaverd, VCawley, AHancock, GThe 248 nm photolysis of NO2 results in an inverted vibrational distribution in NO(v) which agrees well with previous REMPI measurements. It was shown that the quenching of the higher levels in collisions with NO2 have clear importance of resonance energy transfer to the NO2(0,0,1) level. Emission from NO2 was found, produced from the photolysis of N2O4, and its spectral signature was similar to that resulting from electronic excitation of NO2.
spellingShingle Morrell, C
Breheny, C
Haverd, V
Cawley, A
Hancock, G
The 248 nm photolysis of NO2/N2O4: Time-resolved Fourier transform infrared emission from NO and NO2, and quenching of NO (v=5-8)
title The 248 nm photolysis of NO2/N2O4: Time-resolved Fourier transform infrared emission from NO and NO2, and quenching of NO (v=5-8)
title_full The 248 nm photolysis of NO2/N2O4: Time-resolved Fourier transform infrared emission from NO and NO2, and quenching of NO (v=5-8)
title_fullStr The 248 nm photolysis of NO2/N2O4: Time-resolved Fourier transform infrared emission from NO and NO2, and quenching of NO (v=5-8)
title_full_unstemmed The 248 nm photolysis of NO2/N2O4: Time-resolved Fourier transform infrared emission from NO and NO2, and quenching of NO (v=5-8)
title_short The 248 nm photolysis of NO2/N2O4: Time-resolved Fourier transform infrared emission from NO and NO2, and quenching of NO (v=5-8)
title_sort 248 nm photolysis of no2 n2o4 time resolved fourier transform infrared emission from no and no2 and quenching of no v 5 8
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