The 248 nm photolysis of NO2/N2O4: Time-resolved Fourier transform infrared emission from NO and NO2, and quenching of NO (v=5-8)
The 248 nm photolysis of NO2 results in an inverted vibrational distribution in NO(v) which agrees well with previous REMPI measurements. It was shown that the quenching of the higher levels in collisions with NO2 have clear importance of resonance energy transfer to the NO2(0,0,1) level. Emission f...
Main Authors: | , , , , |
---|---|
Format: | Journal article |
Language: | English |
Published: |
2002
|
_version_ | 1826275170603499520 |
---|---|
author | Morrell, C Breheny, C Haverd, V Cawley, A Hancock, G |
author_facet | Morrell, C Breheny, C Haverd, V Cawley, A Hancock, G |
author_sort | Morrell, C |
collection | OXFORD |
description | The 248 nm photolysis of NO2 results in an inverted vibrational distribution in NO(v) which agrees well with previous REMPI measurements. It was shown that the quenching of the higher levels in collisions with NO2 have clear importance of resonance energy transfer to the NO2(0,0,1) level. Emission from NO2 was found, produced from the photolysis of N2O4, and its spectral signature was similar to that resulting from electronic excitation of NO2. |
first_indexed | 2024-03-06T22:54:38Z |
format | Journal article |
id | oxford-uuid:5ff3ad70-7993-47e2-a617-d4e2ef09251a |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-06T22:54:38Z |
publishDate | 2002 |
record_format | dspace |
spelling | oxford-uuid:5ff3ad70-7993-47e2-a617-d4e2ef09251a2022-03-26T17:50:14ZThe 248 nm photolysis of NO2/N2O4: Time-resolved Fourier transform infrared emission from NO and NO2, and quenching of NO (v=5-8)Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:5ff3ad70-7993-47e2-a617-d4e2ef09251aEnglishSymplectic Elements at Oxford2002Morrell, CBreheny, CHaverd, VCawley, AHancock, GThe 248 nm photolysis of NO2 results in an inverted vibrational distribution in NO(v) which agrees well with previous REMPI measurements. It was shown that the quenching of the higher levels in collisions with NO2 have clear importance of resonance energy transfer to the NO2(0,0,1) level. Emission from NO2 was found, produced from the photolysis of N2O4, and its spectral signature was similar to that resulting from electronic excitation of NO2. |
spellingShingle | Morrell, C Breheny, C Haverd, V Cawley, A Hancock, G The 248 nm photolysis of NO2/N2O4: Time-resolved Fourier transform infrared emission from NO and NO2, and quenching of NO (v=5-8) |
title | The 248 nm photolysis of NO2/N2O4: Time-resolved Fourier transform infrared emission from NO and NO2, and quenching of NO (v=5-8) |
title_full | The 248 nm photolysis of NO2/N2O4: Time-resolved Fourier transform infrared emission from NO and NO2, and quenching of NO (v=5-8) |
title_fullStr | The 248 nm photolysis of NO2/N2O4: Time-resolved Fourier transform infrared emission from NO and NO2, and quenching of NO (v=5-8) |
title_full_unstemmed | The 248 nm photolysis of NO2/N2O4: Time-resolved Fourier transform infrared emission from NO and NO2, and quenching of NO (v=5-8) |
title_short | The 248 nm photolysis of NO2/N2O4: Time-resolved Fourier transform infrared emission from NO and NO2, and quenching of NO (v=5-8) |
title_sort | 248 nm photolysis of no2 n2o4 time resolved fourier transform infrared emission from no and no2 and quenching of no v 5 8 |
work_keys_str_mv | AT morrellc the248nmphotolysisofno2n2o4timeresolvedfouriertransforminfraredemissionfromnoandno2andquenchingofnov58 AT brehenyc the248nmphotolysisofno2n2o4timeresolvedfouriertransforminfraredemissionfromnoandno2andquenchingofnov58 AT haverdv the248nmphotolysisofno2n2o4timeresolvedfouriertransforminfraredemissionfromnoandno2andquenchingofnov58 AT cawleya the248nmphotolysisofno2n2o4timeresolvedfouriertransforminfraredemissionfromnoandno2andquenchingofnov58 AT hancockg the248nmphotolysisofno2n2o4timeresolvedfouriertransforminfraredemissionfromnoandno2andquenchingofnov58 AT morrellc 248nmphotolysisofno2n2o4timeresolvedfouriertransforminfraredemissionfromnoandno2andquenchingofnov58 AT brehenyc 248nmphotolysisofno2n2o4timeresolvedfouriertransforminfraredemissionfromnoandno2andquenchingofnov58 AT haverdv 248nmphotolysisofno2n2o4timeresolvedfouriertransforminfraredemissionfromnoandno2andquenchingofnov58 AT cawleya 248nmphotolysisofno2n2o4timeresolvedfouriertransforminfraredemissionfromnoandno2andquenchingofnov58 AT hancockg 248nmphotolysisofno2n2o4timeresolvedfouriertransforminfraredemissionfromnoandno2andquenchingofnov58 |