Synthesis and crystal structure of a cumulenic quinoidal porphyrin dimer with strong electronic absorption in the infrared
Quinoidalization results in amazingly intense near-IR absorption in 1 (λ(max) = 1080 nm), whereas the shorter dimer 2 (λ(max) = 780 nm) is less conjugated because steric interactions force it into a contorted geometry. The crystal structure of 1 shows that the 62-atom chromophore is bow-shaped in th...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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2000
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| _version_ | 1826275212071534592 |
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| author | Blake, I Rees, L Claridge, T Anderson, H |
| author_facet | Blake, I Rees, L Claridge, T Anderson, H |
| author_sort | Blake, I |
| collection | OXFORD |
| description | Quinoidalization results in amazingly intense near-IR absorption in 1 (λ(max) = 1080 nm), whereas the shorter dimer 2 (λ(max) = 780 nm) is less conjugated because steric interactions force it into a contorted geometry. The crystal structure of 1 shows that the 62-atom chromophore is bow-shaped in the solid state. |
| first_indexed | 2024-03-06T22:55:16Z |
| format | Journal article |
| id | oxford-uuid:602638c0-02d8-4cfd-8bbd-6ef2da3ba070 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T22:55:16Z |
| publishDate | 2000 |
| record_format | dspace |
| spelling | oxford-uuid:602638c0-02d8-4cfd-8bbd-6ef2da3ba0702022-03-26T17:51:33ZSynthesis and crystal structure of a cumulenic quinoidal porphyrin dimer with strong electronic absorption in the infraredJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:602638c0-02d8-4cfd-8bbd-6ef2da3ba070EnglishSymplectic Elements at Oxford2000Blake, IRees, LClaridge, TAnderson, HQuinoidalization results in amazingly intense near-IR absorption in 1 (λ(max) = 1080 nm), whereas the shorter dimer 2 (λ(max) = 780 nm) is less conjugated because steric interactions force it into a contorted geometry. The crystal structure of 1 shows that the 62-atom chromophore is bow-shaped in the solid state. |
| spellingShingle | Blake, I Rees, L Claridge, T Anderson, H Synthesis and crystal structure of a cumulenic quinoidal porphyrin dimer with strong electronic absorption in the infrared |
| title | Synthesis and crystal structure of a cumulenic quinoidal porphyrin dimer with strong electronic absorption in the infrared |
| title_full | Synthesis and crystal structure of a cumulenic quinoidal porphyrin dimer with strong electronic absorption in the infrared |
| title_fullStr | Synthesis and crystal structure of a cumulenic quinoidal porphyrin dimer with strong electronic absorption in the infrared |
| title_full_unstemmed | Synthesis and crystal structure of a cumulenic quinoidal porphyrin dimer with strong electronic absorption in the infrared |
| title_short | Synthesis and crystal structure of a cumulenic quinoidal porphyrin dimer with strong electronic absorption in the infrared |
| title_sort | synthesis and crystal structure of a cumulenic quinoidal porphyrin dimer with strong electronic absorption in the infrared |
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