Voltammetry at porous electrodes: A theoretical study
Theory is presented to simulate both chronoamperometry and cyclic voltammetry at porous electrodes fabricated by means of electro-deposition around spherical templates. A theoretical method to extract heterogeneous rate constants for quasireversible and irreversible systems is proposed by the approx...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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Elsevier
2014
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| _version_ | 1797071700473413632 |
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| author | Barnes, E Chena, X Li, P Compton, R |
| author_facet | Barnes, E Chena, X Li, P Compton, R |
| author_sort | Barnes, E |
| collection | OXFORD |
| description | Theory is presented to simulate both chronoamperometry and cyclic voltammetry at porous electrodes fabricated by means of electro-deposition around spherical templates. A theoretical method to extract heterogeneous rate constants for quasireversible and irreversible systems is proposed by the approximation of decoupling of the diffusion within the porous electrode and of bulk diffusion to the electrode surface. |
| first_indexed | 2024-03-06T22:57:06Z |
| format | Journal article |
| id | oxford-uuid:60ca1a03-cec6-42f7-82dd-cf2448ae05f8 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T22:57:06Z |
| publishDate | 2014 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | oxford-uuid:60ca1a03-cec6-42f7-82dd-cf2448ae05f82022-03-26T17:55:32ZVoltammetry at porous electrodes: A theoretical studyJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:60ca1a03-cec6-42f7-82dd-cf2448ae05f8EnglishSymplectic Elements at OxfordElsevier2014Barnes, EChena, XLi, PCompton, RTheory is presented to simulate both chronoamperometry and cyclic voltammetry at porous electrodes fabricated by means of electro-deposition around spherical templates. A theoretical method to extract heterogeneous rate constants for quasireversible and irreversible systems is proposed by the approximation of decoupling of the diffusion within the porous electrode and of bulk diffusion to the electrode surface. |
| spellingShingle | Barnes, E Chena, X Li, P Compton, R Voltammetry at porous electrodes: A theoretical study |
| title | Voltammetry at porous electrodes: A theoretical study |
| title_full | Voltammetry at porous electrodes: A theoretical study |
| title_fullStr | Voltammetry at porous electrodes: A theoretical study |
| title_full_unstemmed | Voltammetry at porous electrodes: A theoretical study |
| title_short | Voltammetry at porous electrodes: A theoretical study |
| title_sort | voltammetry at porous electrodes a theoretical study |
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