The C-4 stereochemistry of leucocyanidin substrates for anthocyanidin synthase affects product selectivity.
Anthocyanidin synthase (ANS), an iron(II) and 2-oxoglutarate (2OG) dependent oxygenase, catalyses the penultimate step in anthocyanin biosynthesis by oxidation of the 2R,3S,4S-cis-leucoanthocyanidins. It has been believed that in vivo the products of ANS are the anthocyanidins. However, in vitro stu...
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Bibliographic Details
Main Authors: |
Turnbull, J,
Nagle, M,
Seibel, J,
Welford, R,
Grant, G,
Schofield, C |
Format: | Journal article
|
Language: | English |
Published: |
2003
|