The C-4 stereochemistry of leucocyanidin substrates for anthocyanidin synthase affects product selectivity.

Anthocyanidin synthase (ANS), an iron(II) and 2-oxoglutarate (2OG) dependent oxygenase, catalyses the penultimate step in anthocyanin biosynthesis by oxidation of the 2R,3S,4S-cis-leucoanthocyanidins. It has been believed that in vivo the products of ANS are the anthocyanidins. However, in vitro stu...

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Hlavní autoři: Turnbull, J, Nagle, M, Seibel, J, Welford, R, Grant, G, Schofield, C
Médium: Journal article
Jazyk:English
Vydáno: 2003