Electrosynthetic reduction of 1-iodoadamantane forming 1,1'-biadamantane and adamantane in aprotic solvents: insonation switches the mechanism from dimerisation to exclusive monomer formation.
The combination of ultrasound and electrochemistry -sonoelectrochemistry can produce a variety of effects within an electrochemical system including enhanced mass transport, in situ cleaning of an electrode surface, diminution of the diffusion layer, and possible induction of new reactions by sonoch...
Prif Awduron: | Paddon, C, Bhatti, F, Donohoe, T, Compton, R |
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Fformat: | Journal article |
Iaith: | English |
Cyhoeddwyd: |
2007
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Eitemau Tebyg
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Coulometry on the voltammetric timescale: Microdisk potential-step chronoamperometry in aprotic solvents reliably measures the number of electrons transferred in an electrode process simultaneously with the diffusion coefficients of the electroactive species
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The transport limited currents at insonated electrodes
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