PERIPHERAL CHEMICAL-REACTIONS
Forward scattering of the products of direct exoergic atom transfer reactions is proposed as an indication for a peripheral attraction: a reaction in which an atom at the periphery of the reactants is abstracted. Model computations for the O(1D) + N2O reaction are used to illustrate the proposed mec...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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1993
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| _version_ | 1826275569698865152 |
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| author | Bennun, M Brouard, M Simons, J Levine, R |
| author_facet | Bennun, M Brouard, M Simons, J Levine, R |
| author_sort | Bennun, M |
| collection | OXFORD |
| description | Forward scattering of the products of direct exoergic atom transfer reactions is proposed as an indication for a peripheral attraction: a reaction in which an atom at the periphery of the reactants is abstracted. Model computations for the O(1D) + N2O reaction are used to illustrate the proposed mechanism. The opacity function has a peak at higher impact parameters which is correlated with the forward scattering. Potential energy surfaces which do not manifest peripheral attraction lead to backwards scattering of the products. © 1993. |
| first_indexed | 2024-03-06T23:00:44Z |
| format | Journal article |
| id | oxford-uuid:620284d7-80d2-4ad3-aea1-fed9bad85da8 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T23:00:44Z |
| publishDate | 1993 |
| record_format | dspace |
| spelling | oxford-uuid:620284d7-80d2-4ad3-aea1-fed9bad85da82022-03-26T18:03:38ZPERIPHERAL CHEMICAL-REACTIONSJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:620284d7-80d2-4ad3-aea1-fed9bad85da8EnglishSymplectic Elements at Oxford1993Bennun, MBrouard, MSimons, JLevine, RForward scattering of the products of direct exoergic atom transfer reactions is proposed as an indication for a peripheral attraction: a reaction in which an atom at the periphery of the reactants is abstracted. Model computations for the O(1D) + N2O reaction are used to illustrate the proposed mechanism. The opacity function has a peak at higher impact parameters which is correlated with the forward scattering. Potential energy surfaces which do not manifest peripheral attraction lead to backwards scattering of the products. © 1993. |
| spellingShingle | Bennun, M Brouard, M Simons, J Levine, R PERIPHERAL CHEMICAL-REACTIONS |
| title | PERIPHERAL CHEMICAL-REACTIONS |
| title_full | PERIPHERAL CHEMICAL-REACTIONS |
| title_fullStr | PERIPHERAL CHEMICAL-REACTIONS |
| title_full_unstemmed | PERIPHERAL CHEMICAL-REACTIONS |
| title_short | PERIPHERAL CHEMICAL-REACTIONS |
| title_sort | peripheral chemical reactions |
| work_keys_str_mv | AT bennunm peripheralchemicalreactions AT brouardm peripheralchemicalreactions AT simonsj peripheralchemicalreactions AT leviner peripheralchemicalreactions |