Electrolyte tuning of electrode potentials: the one electron vs. two electron reduction of anthraquinone-2-sulfonate in aqueous media.
The electrode potentials of quinone redox centres in aqueous solutions can be tuned by varying the electrolyte cation identity. The phenomenon is due to the ion pairing effect of the tetra-n-butylammonium cation with the semiquinone intermediate species.
| Հիմնական հեղինակներ: | , , , , |
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| Ձևաչափ: | Journal article |
| Լեզու: | English |
| Հրապարակվել է: |
2011
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| _version_ | 1826275582970691584 |
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| author | Li, Q Batchelor-McAuley, C Lawrence, N Hartshorne, R Compton, R |
| author_facet | Li, Q Batchelor-McAuley, C Lawrence, N Hartshorne, R Compton, R |
| author_sort | Li, Q |
| collection | OXFORD |
| description | The electrode potentials of quinone redox centres in aqueous solutions can be tuned by varying the electrolyte cation identity. The phenomenon is due to the ion pairing effect of the tetra-n-butylammonium cation with the semiquinone intermediate species. |
| first_indexed | 2024-03-06T23:00:56Z |
| format | Journal article |
| id | oxford-uuid:6216e81e-7cfc-4beb-a6b4-162d5b9ebd21 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T23:00:56Z |
| publishDate | 2011 |
| record_format | dspace |
| spelling | oxford-uuid:6216e81e-7cfc-4beb-a6b4-162d5b9ebd212022-03-26T18:04:05ZElectrolyte tuning of electrode potentials: the one electron vs. two electron reduction of anthraquinone-2-sulfonate in aqueous media.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:6216e81e-7cfc-4beb-a6b4-162d5b9ebd21EnglishSymplectic Elements at Oxford2011Li, QBatchelor-McAuley, CLawrence, NHartshorne, RCompton, RThe electrode potentials of quinone redox centres in aqueous solutions can be tuned by varying the electrolyte cation identity. The phenomenon is due to the ion pairing effect of the tetra-n-butylammonium cation with the semiquinone intermediate species. |
| spellingShingle | Li, Q Batchelor-McAuley, C Lawrence, N Hartshorne, R Compton, R Electrolyte tuning of electrode potentials: the one electron vs. two electron reduction of anthraquinone-2-sulfonate in aqueous media. |
| title | Electrolyte tuning of electrode potentials: the one electron vs. two electron reduction of anthraquinone-2-sulfonate in aqueous media. |
| title_full | Electrolyte tuning of electrode potentials: the one electron vs. two electron reduction of anthraquinone-2-sulfonate in aqueous media. |
| title_fullStr | Electrolyte tuning of electrode potentials: the one electron vs. two electron reduction of anthraquinone-2-sulfonate in aqueous media. |
| title_full_unstemmed | Electrolyte tuning of electrode potentials: the one electron vs. two electron reduction of anthraquinone-2-sulfonate in aqueous media. |
| title_short | Electrolyte tuning of electrode potentials: the one electron vs. two electron reduction of anthraquinone-2-sulfonate in aqueous media. |
| title_sort | electrolyte tuning of electrode potentials the one electron vs two electron reduction of anthraquinone 2 sulfonate in aqueous media |
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