Electrolyte tuning of electrode potentials: the one electron vs. two electron reduction of anthraquinone-2-sulfonate in aqueous media.

Electrolyte tuning of electrode potentials: the one electron vs. two electron reduction of anthraquinone-2-sulfonate in aqueous media.

The electrode potentials of quinone redox centres in aqueous solutions can be tuned by varying the electrolyte cation identity. The phenomenon is due to the ion pairing effect of the tetra-n-butylammonium cation with the semiquinone intermediate species.

書目詳細資料
Main Authors:	Li, Q, Batchelor-McAuley, C, Lawrence, N, Hartshorne, R, Compton, R
格式:	Journal article
語言:	English
出版:	2011

相似書籍

The anthraquinone mediated one-electron reduction of oxygen in acetonitrile
由: Nissim, R, et al.
出版: (2012)

Voltammetric characterization of DNA intercalators across the full pH range: anthraquinone-2,6-disulfonate and anthraquinone-2-sulfonate.
由: Batchelor-McAuley, C, et al.
出版: (2010)

Semiquinone intermediates in the two-electron reduction of quinones in aqueous media and their exceptionally high reactivity towards oxygen reduction.
由: Li, Q, et al.
出版: (2011)

Anomalous solubility of oxygen in acetonitrile/water mixture containing tetra-n-butylammonium perchlorate supporting electrolyte; the solubility and diffusion coefficient of oxygen in anhydrous acetonitrile and aqueous mixtures
由: Li, Q, et al.
出版: (2013)

Voltammetry of multi-electron electrode processes of organic species
由: Batchelor-McAuley, C, et al.
出版: (2012)

Glassy carbon tubular electrodes for the reduction of oxygen to hydrogen peroxide.
由: Li, Q, et al.
出版: (2013)

Voltammetric Responses of Surface-Bound and Solution-Phase Anthraquinone Moieties in the Presence of Unbuffered Aqueous Media
由: Batchelor-McAuley, C, et al.
出版: (2011)

Electrode kinetics at carbon electrodes and the density of electronic states.
由: Nissim, R, et al.
出版: (2012)

Voltammetry at graphite electrodes: The oxidation of hexacyanoferrate (II) (ferrocyanide) does not exhibit pure outer-sphere electron transfer kinetics and is sensitive to pre-exposure of the electrode to organic solvents
由: Xiong, L, et al.
出版: (2011)

Anomalous solubility of oxygen in acetonitrile/water mixture containing tetra-n-butylammonium perchlorate supporting electrolyte; The solubility and diffusion coefficient of oxygen in anhydrous acetonitrile and aqueous mixtures
由: Li, Q, et al.
出版: (2013)

Anthraquinone monosulfonate adsorbed on graphite shows two very different rates of electron transfer: surface heterogeneity due to basal and edge plane sites.
由: Neumann, C, et al.
出版: (2011)

Thin-Film Modified Rotating Disk Electrodes: Models of Electron-Transfer Kinetics for Passive and Electroactive Films
由: Batchelor-McAuley, C, et al.
出版: (2014)

Application of Marcus-Hush-Chidsey Theory to Two Electron Systems. The Influence of Electrode Material on the Electro-Reduction Kinetics of Covalently Attached 2-Anthraquinonyl Groups: Gold Vs. Carbon
由: Kozub, B, et al.
出版: (2011)

Tuning Redox Potential of Anthraquinone-2-Sulfonate (AQS) by Chemical Modification to Facilitate Electron Transfer From Electrodes in Shewanella oneidensis
由: Ning Xu, et al.
出版: (2021-08-01)

Tafel-Volmer electrode reactions: The influence of electron-transfer kinetics
由: Lin, C, et al.
出版: (2015)

The indirect electrochemical detection and quantification of DNA through its co-adsorption with anthraquinone monosulphonate on graphitic and multi-walled carbon nanotube screen printed electrodes.
由: Xiong, L, et al.
出版: (2011)

Altered Electrochemistry at Graphene- or Alumina-Modified Electrodes: Catalysis vs Electrocatalysis in Multistep Electrode Processes
由: Poon, J, et al.
出版: (2015)

Aqueous voltammetry in the near absence of electrolyte
由: Li, X, et al.
出版: (2017)

On the adiabaticity of electrode processes: Effect of the supporting electrolyte cation on the kinetics of electroreduction of 3-nitrophenolate
由: Laborda, E, et al.
出版: (2013)

Electrocatalysis via intrinsic surface quinones mediating electron transfer to and from carbon electrodes
由: Li, D, et al.
出版: (2020)

Electrochemical oxidation of guanine: electrode reaction mechanism and tailoring carbon electrode surfaces to switch between adsorptive and diffusional responses.
由: Li, Q, et al.
出版: (2010)

Marcus-Hush-Chidsey theory of electron transfer to and from species bound at a non-uniform electrode surface: Theory and experiment
由: Henstridge, M, et al.
出版: (2011)

The synthesis and characterisation of controlled thin sub-monolayer films of 2-anthraquinonyl groups on graphite surfaces
由: Li, Q, et al.
出版: (2011)

Use of 'split waves' for the measurement of electrocatalytic kinetics: methyl viologen mediated oxygen reduction on a boron-doped diamond electrode.
由: Lin, Q, et al.
出版: (2013)

Two-Electron, Two-Proton Oxidation of Catechol: Kinetics and Apparent Catalysis
由: Lin, Q, et al.
出版: (2015)

Carbon dioxide reduction in room temperature ionic liquids: the effect of the choice of electrode material, cation, and anion
由: Tanner, E, et al.
出版: (2016)

Organic Nanoparticles: Mechanism of Electron Transfer to Indigo Nanoparticles
由: Cheng, W, et al.
出版: (2014)

Multi-electron transfer to and from organic molecules
由: Batchelor-McAuley, C, et al.
出版: (2012)

Nickel Nanoparticle Modified BDD Electrode Shows an Electrocatalytic Response to Adenine and DNA in Aqueous Alkaline Media
由: Harfield, J, et al.
出版: (2011)

Nanoparticle capping agent controlled electron-transfer dynamics in ionic liquids.
由: Tanner, E, et al.
出版: (2016)

Nanoimpacts reveal the electron-transfer kinetics of the ferrocene/ferrocenium couple immobilised on graphene nanoplatelets
由: Wu, H, et al.
出版: (2016)

Improving single-carbon-nanotube–electrode contacts using molecular electronics
由: Krittayavathananon, A, et al.
出版: (2017)

A flow system for hydrogen peroxide production at reticulated vitreous carbon via electroreduction of oxygen
由: Li, Q, et al.
出版: (2014)

Thin film-modified electrodes: a model for the charge transfer resistance in electrochemical impedance spectroscopy
由: Eloul, S, et al.
出版: (2014)

'Sticky electrodes' for the detection of silver nanoparticles.
由: Tschulik, K, et al.
出版: (2013)

Electrolyte induced electrical dis-connection between single graphene nanoplatelets and an electrode
由: Krittayavathananon, A, et al.
出版: (2018)

Evaluation of Electrochemical Stability of Sulfonated Anthraquinone-Based Acidic Electrolyte for Redox Flow Battery Application
由: Petr Mazúr, et al.
出版: (2021-04-01)

Electrochemical measurement of the dissolved oxygen concentration in water in the absence of deliberately added supporting electrolyte
由: Clark, R, et al.
出版: (2017)

Square wave voltammetry at disc microelectrodes for characterization of two electron redox processes.
由: Laborda, E, et al.
出版: (2012)

Electrode-particle impacts: a users guide
由: Sokolov, S, et al.
出版: (2016)