The effect of 4 '-substituents on the kinetics of ligand substitution in 2,2 ': 6 ',2 ''-terpyridine platinum(II) complexes
The rates of hydrolysis of five (4′-substituted-2,2′:6′,2′-terpyridine) platinum(II) (n-propylamine) complexes exhibit a high sensitivity to the electronic properties of the terpyridine ligand; analysis using the Hammett relationship gives a ρ value of +2.34.
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2000
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| Summary: | The rates of hydrolysis of five (4′-substituted-2,2′:6′,2′-terpyridine) platinum(II) (n-propylamine) complexes exhibit a high sensitivity to the electronic properties of the terpyridine ligand; analysis using the Hammett relationship gives a ρ value of +2.34. |
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