Homogeneous catalysis of electrochemical reactions. Channel electrode voltammetry and the EC′ mechanism

Homogeneous catalysis of electrochemical reactions. Channel electrode voltammetry and the EC′ mechanism

The shape of the current-voltage curves at a channel electrode have been calculated for the various situations of the catalytic (EC’) mechanism. In particular the halfwave potential and limiting current are found to be highly sensitive to the solution-flow rate and to the concentrations of the media...

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Bibliografiske detaljer
Main Authors:	Compton, R, Fisher, A, Spackman, R
Format:	Journal article
Udgivet:	1992

Lignende værker

Homogeneous catalysis of electrochemical reactions: “Split waves” at the rotating disc electrode
af: Compton, R, et al.
Udgivet: (1990)

HOMOGENEOUS CATALYSIS OF ELECTROCHEMICAL REACTIONS - MECHANISTIC RESOLUTION VIA ROTATING-DISK ELECTRODE VOLTAMMETRIC WAVESHAPE ANALYSIS
af: Compton, R, et al.
Udgivet: (1989)

Linear sweep voltammetry at the tubular electrode: Theory of EC mechanisms
af: Thompson, M, et al.
Udgivet: (2006)

The EC′ mechanism: Split waves at the channel electrode
af: Fisher, A, et al.
Udgivet: (1992)

THE WALL-JET ELECTRODE AND THE STUDY OF ELECTRODE-REACTION MECHANISMS - THE EC REACTION
af: Compton, R, et al.
Udgivet: (1990)

Simulation of square-wave voltammetry at a channel electrode: E, EC and ECE processes
af: Miles, AB, et al.
Udgivet: (2001)

Linear sweep voltammetry at the tubular electrode: Theory of EC2 mechanisms
af: Streeter, I, et al.
Udgivet: (2006)

THE WALL-JET ELECTRODE AND THE STUDY OF ELECTRODE-REACTION MECHANISMS - THE EC (CATALYTIC) MECHANISM
af: Compton, R, et al.
Udgivet: (1991)

ROTATING-DISK ELECTRODE VOLTAMMETRY - THE CATALYTIC MECHANISM (EC) AND ITS NUANCES
af: Compton, R, et al.
Udgivet: (1988)

Simulation of square-wave voltammetry: EC and ECE electrode processes
af: Miles, AB, et al.
Udgivet: (2000)

HYDRODYNAMIC VOLTAMMETRY WITH CHANNEL ELECTRODES - MICRODISK ELECTRODES
af: Booth, J, et al.
Udgivet: (1995)

CHANNEL-ELECTRODE VOLTAMMETRY - WAVESHAPE ANALYSIS OF THE CURRENT-VOLTAGE CURVES OF EC2 AND DISP2 PROCESSES
af: Compton, R, et al.
Udgivet: (1989)

SPECTROFLUOROMETRIC HYDRODYNAMIC VOLTAMMETRY - THE INVESTIGATION OF ELECTRODE-REACTION MECHANISMS
af: Compton, R, et al.
Udgivet: (1994)

MASS-TRANSPORT IN CHANNEL ELECTRODES - THE APPLICATION OF THE BACKWARDS IMPLICIT METHOD TO ELECTRODE-REACTIONS (EC, ECE AND DISP) INVOLVING COUPLED HOMOGENEOUS KINETICS
af: Compton, R, et al.
Udgivet: (1988)

Heterogeneous and homogeneous EC and ECE processes at channel electrodes: Analytical wave shape theory
af: Morland, P, et al.
Udgivet: (1999)

A GENERAL COMPUTATIONAL APPROACH TO LINEAR SWEEP VOLTAMMETRY AT CHANNEL ELECTRODES
af: Fisher, A, et al.
Udgivet: (1992)

LINEAR SWEEP VOLTAMMETRY AT CHANNEL ELECTRODES
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Udgivet: (1986)

VOLTAMMETRY AT C-60-MODIFIED ELECTRODES
af: Compton, R, et al.
Udgivet: (1993)

HYDRODYNAMIC VOLTAMMETRY WITH MICROELECTRODES - CHANNEL MICROBAND ELECTRODES - THEORY AND EXPERIMENT
af: Compton, R, et al.
Udgivet: (1993)

THE THEORY OF EC REACTIONS AT TUBULAR ELECTRODES
af: Coles, B, et al.
Udgivet: (1981)

ROTATING-DISK ELECTRODE VOLTAMMETRY - WAVESHAPE ANALYSIS FOR DISP2 AND EC2 PROCESSES
af: Compton, R, et al.
Udgivet: (1988)

DOUBLE-CHANNEL ELECTRODES - HOMOGENEOUS KINETICS AND COLLECTION EFFICIENCY MEASUREMENTS
af: Fisher, A, et al.
Udgivet: (1991)

Anodic stripping voltammetry at hydrodynamic mercury electrodes. Square wave voltammetry: Numerical theory for electrochemically reversible systems
af: Ball, J, et al.
Udgivet: (1998)

Voltammetry at micro-mesh electrodes
af: Wadhawan, J, et al.
Udgivet: (2003)

Cyclic Voltammetry of the EC' Mechanism at Hemispherical Particles and Their Arrays: The Split Wave
af: Ward, K, et al.
Udgivet: (2011)

Hydrodynamic voltammetry with channel microband electrodes: Axial diffusion effects
af: Alden, J, et al.
Udgivet: (1996)

Variable-temperature microelectrode voltammetry: Application to diffusion coefficients and electrode reaction mechanisms
af: Jacob, SR, et al.
Udgivet: (1999)

Hydrodynamic voltammetry with channel microband electrodes: The simulation of voltammetric waveshapes
af: Bidwell, M, et al.
Udgivet: (1996)

HYDRODYNAMIC VOLTAMMETRY WITH CHANNEL MICROBAND ELECTRODES - ALTERNATING-CURRENT IMPEDANCE MEASUREMENTS
af: Compton, R, et al.
Udgivet: (1995)

WALL-JET ELECTRODE LINEAR SWEEP VOLTAMMETRY
af: Compton, R, et al.
Udgivet: (1992)

HYDRODYNAMIC VOLTAMMETRY WITH CHANNEL MICROBAND ELECTRODES - POTENTIAL STEP TRANSIENTS
af: Compton, R, et al.
Udgivet: (1994)

Using microelectrode square-wave voltammetry to monitor the progress of complex homogeneous chemical reactions
af: Macfic, G, et al.
Udgivet: (2002)

A CRITICAL-ASSESSMENT OF THE THEORIES FOR LINEAR SWEEP VOLTAMMETRY OF REVERSIBLE ELECTRODE PROCESSES AT A CHANNEL ELECTRODE
af: Compton, R, et al.
Udgivet: (1989)

Voltammetry at spatially heterogeneous electrodes
af: Davies, T, et al.
Udgivet: (2005)

Voltammetry at micro-mesh electrodes
af: Wadhawan Jay D., et al.
Udgivet: (2003-01-01)

Modelling homogeneous kinetics in the double channel electrode
af: Thompson, M, et al.
Udgivet: (2005)

ROTATING-DISK ELECTRODE VOLTAMMETRY - DIGITAL-SIMULATION OF THE CURRENT VOLTAGE BEHAVIOR OF ELECTRODE PROCESSES INVOLVING REVERSIBLE ELECTRON-TRANSFER AND COUPLED HOMOGENEOUS KINETICS
af: Compton, R, et al.
Udgivet: (1989)

The application of fast scan cyclic voltammetry to the high speed channel electrode
af: Rees, N, et al.
Udgivet: (2003)

HYDRODYNAMIC VOLTAMMETRY WITH CHANNEL MICROBAND ELECTRODES - RESOLUTION OF ECE AND DISP1 PROCESSES
af: Compton, R, et al.
Udgivet: (1994)

Channel microband electrode arrays for mechanistic electrochemistry. Two-dimensional voltammetry: Electrode kinetics
af: Prieto, F, et al.
Udgivet: (1999)