Enhanced coherence by coupling spins through a delocalized π-system: Vanadyl porphyrin dimers

Vanadium(IV) magnetic centers are prime candidates for molecular quantum units. One long-standing question is how to obtain a scaffold that connects multiple centers and allows two communication modalities: magnetic and electronic. We have synthesized and studied a selection of vanadyl porphyrin dim...

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Hlavní autoři: Pozo, I, Huang, Z, Alexandropoulos, DI, Slota, M, Tkach, I, Bennati, M, Deng, J-R, Stawski, W, Horton, PN, Myers, WK, Kong, F, Lombardi, F, Bogani, L, Anderson, HL, Coles, SJ
Médium: Journal article
Jazyk:English
Vydáno: Cell Press 2024