A redox-induced spin-state cascade in a mixed-valent Fe3 (μ3 -O) triangle.

A redox-induced spin-state cascade in a mixed-valent Fe3 (μ3 -O) triangle.

One-electron reduction of a pyrazolate-bridged triangular Fe3 (μ3 -O) core induces a cascade wherein all three metal centers switch from high-spin Fe(3+) to low-spin Fe(2.66+) . This hypothesis is supported by spectroscopic data ((1) H-NMR, UV-vis-NIR, infra-red, (57) Fe-Mössbauer, EPR), X-ray cryst...

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Bibliografiska uppgifter
Huvudupphovsmän:	Govor, E, Al-Ameed, K, Chakraborty, I, Coste, C, Govor, O, Sanakis, Y, McGrady, J, Raptis, R
Materialtyp:	Journal article
Språk:	English
Publicerad:	Wiley 2016

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